November 2006

TECHNICAL ASSISTANCE FOR IRON GATE
SEDIMENTS EVALUATION

Report on Support Activities for the DRP
Component on Iron Gates Sediments Evaluation,
provided by VITUKI

---

AUTHORS

PREPARED BY:
VITUKI Environmental Protection and Water Management Research Institute

AUTHORS:
Dr. Béla Csányi
Ms. Mária Bihari
















VITUKI Environmental Protection and Water
Management Research Institute
H-1095 Budapest, Kvassay J. út 1.

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Technical Assistance for Iron Gate Sediments Evaluation
page 3
TABLE OF CONTENTS
1.
Project objectives................................................................................................5
2.
Approach of work in line with the required services ..................................................5
2.1.
Provision of a vessel for sampling mission ...........................................................5
2.2.
Collection of samples .......................................................................................5
2.3.
Analysis of samples .........................................................................................6
3.
Results and conclusions .......................................................................................6
3.1.
Provision of a vessel for sampling mission ...........................................................6
3.2.
Collection of samples .......................................................................................6
3.3.
Analysis of samples .........................................................................................7
3.4.
Applied analytical methods for the analysis of sediment samples in VITUKI ..............7
3.5.
Results of measurements .................................................................................9
3.6.
Conclusion ................................................................................................... 10

Annex: Tables and Figures





ABBREVIATIONS

DRP
Danube Regional Project
VITUKI Kht.
VITUKI Environmental Protection and Water Management Research Institute










UNDP/GEF DANUBE REGIONAL PROJECT

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page 4

EXECUTIVE SUMMARY

DRP's Component 4.2 has the objective to assess the sediment quality in the Iron Gate
Reservoir and to prepare initial recommendations for future protection of the Danube River and
Black Sea. The project is an assessment of data and information on the Iron Gate sediments
and is a step in identifying gaps in the available information.
This assignment (Technical assistance for Iron Gate sediments evaluation) aimed at assisting
the Romanian and Serbian National Teams by providing a sampling ship and collection and
analysis of samples for direct comparison with the National Teams. The sampling survey was
carried out in September 2006 by the ship ARGUS. Grab samples and core samples were taken
at the preselected 10 sections in the Iron Gate reservoir region in the Danube reach 928-1107
km.
The determinands total phosphorus, organic nitrogen, heavy metals (mercury, cadmium, lead,
nickel, chromium, arsenic, copper, zinc), exctractable petroleum hydrocarbons, organochlorine
pesticides (DDT, lindane, aldrin, endrin, dieldrin), nonylphenol, octylphenol, pentachlorphenol,
di(2-ethylhexyl)phthalate, PAHs, PCBs and particle size distribution were analyzed by widely
used methods in the laboratory of VITUKI Kht.
The analytical results indicate the spatial concentration distribution of different contaminants in
the bottom sediment of the Iron Gate reservoir.
The analytical results of the measurements in the VITUKI laboratory can be used for
comparative analysis together with the results of the Romanian and Serbian teams for the same
samples.
The analytical results contribute to the assessment of sediment contamination in the Iron Gate
reservoir.






VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation
page 5

1. PROJECT OBJECTIVES
The overall objective of the DRP's Component 4.2 is to assess the sediment quality in the Iron
Gate Reservoir and to prepare initial recommendations for future protection of the Danube River
and Black Sea. The specific objectives include:
1.
Collecting and reviewing the existing data and information on present situation
(especially heavy metals, nutrients, silicates and other dangerous substances);
2.
Assessing the main types and quantities of dangerous substances;
3.
Assessing the potential environmental impacts on the Danube and the Black Sea;
4.
Forecasting development for a period of 20 years;
5.
Discussing possible precautionary and rehabilitation measures for the Danube and
the Black Sea;
6.
Preparing recommendations for dealing with this problem in the forthcoming decade
(measures to be included in the Joint Action Programme of the ICPDR);
7.
Undertaking sampling and analysis as agreed by the overall project team
8.
Proposing further monitoring programmes.
This project is an assessment of data and information on the Iron Gate sediments and is a step
in identifying any gaps in the available information leading to the need for future investment
(e.g. international donors) programmes for remediation.
The objectives of this assignment (Provision of Support Activities) is to assist the National
Teams (under the direction of the Project Co-ordinator) by:
> Providing a sampling ship;
> Collection and analysis of samples for direct comparison with the National Teams.


2. APPROACH OF WORK IN LINE WITH THE REQUIRED
SERVICES
To achieve the objectives of provision of support activities the following tasks were undertaken
by the Contractor:
2.1. Provision of a vessel for sampling mission
The International Laboratory was required to obtain the services of an appropriate vessel to
enable samples to be collected from the Iron Gate Reservoir.
2.2. Collection of samples
The International Laboratory was required to collect samples (as agreed by the project team)
for subsequent analysis.

UNDP/GEF DANUBE REGIONAL PROJECT

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Results and conclusions
page 6
2.3. Analysis of samples
The International Laboratory was required to analyse the samples for an agreed list of
determinands.


3. RESULTS AND CONCLUSIONS
3.1. Provision of a vessel for sampling mission
The ship "Argus" (Serbia) was selected for sampling in the Iron Gate region. The Serbian
Ministry of Science and Environmental Protection agreed to rent the ship Argus for the project in
the period 10-15 September 2006.

3.2. Collection of samples
A plan was prepared and discussed for sediment sampling sites and sampling schedule.
Table 1 Proposed sediment sampling sites:
No.
Name of sampling site
km
Grab sample+
Core sample++
1
Upstream of Velika Morava
1107
+

2
Downstream of Velika Morava
1097
+

3 Ram/Stara
Palanka
1077
+
+
4
Veliko Gradiste / Belobresca
1061
+

5
Golubac / Coronini
1043
+

6
Dobra / Lubcova
1022
+

7
Donji Milanovac
990
+
+
8
Dubova
971
+

9
Orsova
955
+
+
10
Mala Vrbica / Simian
927
+
+
+ upper 10 cm layer of sediment
++vertical profile (10 cm deep layers, max. 1 m deep profile)

VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation
page 7

Table 2 Schedule of sampling:
Day 1
Departure: Belgrade
Arrival:
Veliko
Gradiste

Sampling at sites No. 1-4
Day 2
Departure: Veliko Gradiste

Arrival: Donji Milanovac

Sampling at sites No. 5-7
Day 3
Departure: Donji Milanovac

Arrival: Mala Vrbica

Sampling at sites No. 8-10
Day 4
Departure: Mala Vrbica
Arrival:
Belgrade

The actual sampling sites with GPS co-ordinates and sampling dates are listed in Annex Table 1.

3.3. Analysis of samples
Analysis of grab samples from sampling sites No 1 L and R, 2 L and R, 3 L and R, 4 L and R, 5 L
and R, 6 L and R, 7 L and R, 8 R, 9 L and R, 10 L and R, Core 1077 R, Core 991 R, Core 956 L
were carried out in VITUKI laboratory.
The measured determinands in sediment were: total phosphorus, organic nitrogen, heavy
metals (mercury, cadmium, lead, nickel, chromium, arsenic, copper, zinc), exctractable
petroleum hydrocarbons, organochlorine pesticides (DDT, lindane, aldrin, endrin, dieldrin),
nonylphenol, octylphenol, pentachlorphenol, di(2-ethylhexyl)phthalate, PAHs, PCBs and particle
size distribution.

3.4. Applied analytical methods for the analysis of sediment
samples in VITUKI
The analytical methods of the determinands applied in VITUKI were as follows:

Heavy metals, trace elements (mercury, cadmium, lead, nickel, chromium, arsenic, copper,
zinc)
Sample preparation: microwave digestion of freeze dried sample with nitric acid and hydrogen
peroxide.
Analytical method: AAS flame atomization (in case of mercury cold vapour technique, in case of
arsenic hydride technique)
UNDP/GEF DANUBE REGIONAL PROJECT

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Results and conclusions
page 8

Total phosphorus
Sample preparation: digestion of freeze dried sample with sulphuric acid and later with
hydrogen peroxide.
Analytical method: the ortho-phosphate reacts with molybdenate. It develops blue colour in the
presence of antimon(III) ions, after reduction by ascorbic acid. Measurement at 820 nm.

Organic nitrogen + ammonium-nitrogen
Sample preparation: digestion of freeze dried sample with sulphuric acid and later with
hydrogen peroxide.
Analytical method: after the digestion the resultant ammonium reacts with salicilate and
hypochlorite ion in the presence of nitroprusside-sodium. Colorimetric measurement at 655 nm.

Extractable petroleum hydrocarbons (GC/FID method)
Sample preparation: extraction of wet sediment with acetone plus hexane solution of squalane.
The evaporated residue is dissolved in hexane and cleaned on SPE Si-cartridge. 1-chlor-nonane
is added to the sample.
Chromatographic conditions:
Carrier gas: H2 30 ml/min (0.9 kPa)
Split: 1:60
Column: DB-5, 20 m x 0.25 mm, HP-5 5 % phenyl-methyl-silicone polymer

Di(2-ethyl-hexyl)phthalate
Sample preparation: extraction of wet sediment with acetone plus hexane solution of dipentyl-
phtalate. Second extraction with hexane. The hexane solution is cleaned on SPE Si-cartridge.
Eluation with dichloro-methane.
GC conditions:
Carrier gas: H2 30 ml/min (0.9 kPa)
Split: 1:60
Column: DB-5, 20 m x 0.25 mm, HP-5 5 % phenyl-methyl-silicone polymer

PAHs
Sample preparation: d10-fluoranthene and d12-chrisene (dissolved in methanol) is added to the
sample. The sample is freeze dried and extracted with dichloro-methane in ultrasonic bath.. The
extractum is centrifugated, dried on sodium-sulphate, evaporated by nitrogen , cleaned on SPE
Si-cartridge. Eluation with dichloro-methane, ISTD is added..
GC conditions:
Column: DB-5, 30 m, 0.25 mm, 0.25 µm
Carrier gas: He
VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation
page 9

MS:
Ionisation: El+/SIR, 70 eV, 200µA

Organochlorine pesticides (DDT, lindane, aldrin, endrin dieldrin)
Sample preparation: The sample is freeze dried and extracted with dichloro-methane in
ultrasonic bath.. The extractum is cleaned on SPE Si-cartridge. Eluation with dichloro-methane.
GC conditions:
Column: DB-5ms, 30 m, 0.25 mm, 0.25 µm
Carrier gas: He
MS:
Ionisation: El+/SIR, 70 eV, 200µA
R=4000

PCBs
Sample preparation: The sample is freeze dried and extracted with dichloro-methane in
ultrasonic bath. The extractum is cleaned on SPE Si-cartridge. Eluation with dichloro-methane.
GC conditions:
Column: DB-5ms, 30 m, 0.25 mm, 0.25 µm
Carrier gas: He
MS:
Ionisation: El+/SIR, 70 eV, 200µA
R=4000

Nonylphenol, octylphenol, pentachlorphenol
Sample preparation: The sample is freeze dried and extracted with dichloro-methane in
ultrasonic bath.. The extractum is cleaned on SPE SiOH-cartridge. Eluation with dichloro-
methane. Eluate is dried with nitrogen then derivatization: addition of 2,6-diterciel-butylphenol,
acetic acid anhydride, triethylamin. 1 hour long reaction at 60 oC. Addition of distilled water,
sodium chloride to the cooled sample, extraction with hexane. Analysis with GC-MSD.
Particle size distribution
Granulometric measurement

3.5. Results of measurements
The analytical results (concentrations in dry sediment) are indicated in Annex Table 2.
Figure 1-3. shows selected determinand concentrations in core sample profiles.
Figure 4. shows the particle size distribution results of grab samples.
UNDP/GEF DANUBE REGIONAL PROJECT

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Results and conclusions
page 10

3.6. Conclusions
> The sediment sampling survey was carried out according to the proposed plan: grab
samples and core samples were taken at the preselected sites in the Iron Gate
reservoir region.
> The applied analytical methods are widely used procedures.
> The analytical results indicate the spatial concentration distribution of different
contaminants in the bottom sediment of the Iron Gate reservoir.
> The analytical results of the measurements in the VITUKI laboratory can be used for
comparative analysis together with the results of the Romanian and Serbian teams for
the same samples.
> The analytical results contribute to the assessment of sediment contamination in the
Iron Gate reservoir.

VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 11

ANNEXES


ANNEX
TABLES AND FIGURES


















UNDP/GEF DANUBE REGIONAL PROJECT

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ANNEX 1: Tables and Figures
page 12
TABLE 1 ACTUAL SAMPLING SITES AND SAMPLING DATES

Iron Gates
GPS Coordinates
Km
Location
Sampling Date S. Time
sample
Sample type
Location
Latitude Longitude
index
in Profile
[MM/DD/YYYY] [HH:MM]
number
° ` `` ° ` ``
1
grab
1107 Upstream Velika Morava
L
44 43 33,8 21 00 09.9 2006.09.11
13:30
1
grab
1107 Upstream Velika Morava
R
44 42 58,1 21 00 25,8 2006.09.11
12:50
2
grab
1097 Downstream Velika Morava
L
44 44 16,4 21 07 37,0 2006.09.11
14:45
2
grab
1097 Downstream Velika Morava
R
44 43 44,8 21 07 51,8 2006.09.11
14:57
-
core
1077 Stara Palanka - Ram
R
44 48 33,0 21 19 43,2 2006.09.11
17:00
0-10
cm











-
10-20 cm











-
20-30 cm











-
30-40 cm











-
40-50 cm











-
50-60 cm











-
60-70 cm











-
70-77 cm











3
grab
1072 Bazias
L
44 48 12,9 21 23 31,0 2006.09.11
19:10
3
grab
1072 Bazias
R
44 48 17,3 21 22 48,4 2006.09.11
19:30
4
grab
1061 Veliko Gradiste / Belobresca
L
44 46 33,2 21 29 44,6 2006.09.12
10:00
4
grab
1061 Veliko Gradiste / Belobresca
R
44 46 05.3 21 29 36,3 2006.09.12
10:20
5
grab
1040 Golubac / Koronin
L
44 40 06.7 21 41 20,0 2006.09.12
12:15
5
grab
1040 Golubac / Koronin
R
44 39 40,8 21 41 2,6 2006.09.12
12:00
6
grab
1022 Dobra Lubcova
L
44 38 59,9 21 53 51,3 2006.09.12
14:10
6
grab
1022 Dobra Lubcova
R
44 38 38,7 21 52 56,4 2006.09.12
14:00
7
grab
991 Donji Milanovac
L
44 28 45,4 22 08 35,8 2006.09.13
10:30
7
grab
991 Donji Milanovac
R
44 27 56,3 22 08 15,1 2006.09.13
9:30
-
core
991 Donji Milanovac
L
44 28 45,4 22 08 35,8 2006.09.13
12:00
0-10
cm











-
10-20 cm











VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 13
Iron Gates
GPS Coordinates
Km
Location
Sampling Date S. Time
sample
Sample type
Location
Latitude Longitude
index
in Profile
[MM/DD/YYYY] [HH:MM]
number
° ` `` ° ` ``
-
20-30 cm











-
30-40 cm











-
40-50 cm











-
50-60 cm











-
60-70 cm











-
70-74 cm











-
core
991 Donji Milanovac
R
44 27 56,3 22 08 15,1 2006.09.13
9:45
0-10
cm











-
10-20 cm











-
20-30 cm











-
30-40 cm











-
40-50 cm











-
50-60 cm











-
60-67 cm











no sediment found on the left side








8
grab
971 Dubova
R
44 36 23,0 22 16 24,6 2006.09.13
11:40
9
grab
956 Tekija / Orsova
L
44 41 26,0 22 23 43,9 2006.09.13
13:50
9
grab
956 Tekija / Orsova
R
44 41 03.4 22 24 26,1 2006.09.13
13:20
-
core
956 Tekija / Orsova
L
44 41 26,0 22 23 43,9 2006.09.13
14:00

0-10 cm












10-20 cm












20-30 cm












30-40 cm












40-50 cm












50-60 cm












60-70 cm












70-78 cm












core
956 Tekija / Orsova
R
44 41 03.8 22 24 26,7 2006.09.13
13:30
0-10
cm











UNDP/GEF DANUBE REGIONAL PROJECT

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ANNEX 1: Tables and Figures
page 14
Iron Gates
GPS Coordinates
Km
Location
Sampling Date S. Time
sample
Sample type
Location
Latitude Longitude
index
in Profile
[MM/DD/YYYY] [HH:MM]
number
° ` `` ° ` ``

10-20 cm












20-30 cm












30-40 cm












40-50 cm












50-60 cm












60-70 cm












70-82 cm











10
grab
928 Mala Vrbica / Simian
L
44 37 12,1 22 41 06.9 2006.09.13
19:30
10
grab
928 Mala Vrbica / Simian
R
44 36 29,8 22 40 47,6 2006.09.13
19:00

core
928 Mala Vrbica / Simian
R
44 36 29,8 22 40 47,6 2006.09.13
19:00
0-10
cm












10-20 cm












20-30 cm












30-40 cm












40-50 cm












50-60 cm












60-70 cm












70-80 cm











VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 15
TABLE 2: ANALYTICAL RESULTS OF THE SEDIMENT
INVESTIGATION

Sample code

1-1107-L
1-1107-R
Components Unit
Concentration
Fluoranthene
µg/kg 86
87
Benzo(b)fluoranthene µg/kg 143
136
Benzo(k)fluoranthene µg/kg 95
88
Benzo(a)pyrene
µg/kg 114
103
Indeno(1,2,3 )pyrene µg/kg 66
61
Benzo(g,h,i)perylene
µg/kg 25
23
PCB-28
µg/kg <1
<1
PCB-52
µg/kg <1
<1
PCB-101
µg/kg <1
<1
PCB-118
µg/kg <1
<1
PCB-138
µg/kg <1
<1
PCB-153
µg/kg <1
<1
PCB-180
µg/kg <1
<1
Aldrin
µg/kg <1
<1
Dieldrin
µg/kg <1
<1
Endrin
µg/kg <1
<1
DDT
µg/kg 2,1
1,5
Lindane
µg/kg <1
<1
Octylphenol
µg/kg <5
<5
Nonyphenol
µg/kg 89
86
Pentachlorphenol
µg/kg <5
<5
TPH mg/kg
60
33
DEPH mg/kg
<0,1
0,2
Mercury mg/kg
0,25
0,28
Arsenic mg/kg
13,5
14,2
Cadmium mg/kg
2,6
3,0
Lead mg/kg
60
61
Copper mg/kg
58
47
Zinc mg/kg
247
288
Chromium mg/kg
58
66
Nickel mg/kg
55
84
Total phosphorus
mg/kg
1159
1173
Organic nitrogen
mg/kg
2228
1948

UNDP/GEF DANUBE REGIONAL PROJECT

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ANNEX 1: Tables and Figures
page 16

Sample code

2-1097-L
2-1097-R
Components Unit
Concentration
Fluoranthene
µg/kg 132
84
Benzo(b)fluoranthene
µg/kg 303 108
Benzo(k)fluoranthene
µg/kg 153
56
Benzo(a)pyrene
µg/kg 204
73
Indeno(1,2,3 )pyrene
µg/kg 107
49
Benzo(g,h,i)perylene
µg/kg 51
25
PCB-28
µg/kg <1 <1
PCB-52
µg/kg <1 <1
PCB-101
µg/kg <1 <1
PCB-118
µg/kg <1 <1
PCB-138
µg/kg <1 <1
PCB-153
µg/kg <1 <1
PCB-180
µg/kg <1 <1
Aldrin
µg/kg
< 1
< 1
Dieldrin
µg/kg
< 1
< 1
Endrin
µg/kg
< 1
< 1
DDT
µg/kg 2 <
1
Lindane
µg/kg
< 1
< 1
Octylphenol
µg/kg <5 <5
Nonyphenol
µg/kg 64
96
Pentachlorphenol
µg/kg <5 <5
TPH mg/kg
16
29
DEPH mg/kg
0,26
0,53
Mercury mg/kg
0,27
0,25
Arsenic mg/kg
16,4
18,8
Cadmium mg/kg
3,0
3,0
Lead mg/kg
67
82
Copper mg/kg
66
49
Zinc mg/kg
284
282
Chromium mg/kg
69
100
Nickel mg/kg
71
143
Total phosphorus
mg/kg
1335
1196
Organic nitrogen
mg/kg
2450
1765
VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 17

Sample code

3-1072-L 3-1072-R
Components Unit
Concentration
Fluoranthene
µg/kg 78
62
Benzo(b)fluoranthene
µg/kg 139 107
Benzo(k)fluoranthene
µg/kg 86
71
Benzo(a)pyrene
µg/kg 105
79
Indeno(1,2,3 )pyrene
µg/kg 70
48
Benzo(g,h,i)perylene
µg/kg 25
19
PCB-28
µg/kg <1 <1
PCB-52
µg/kg <1 <1
PCB-101
µg/kg <1 <1
PCB-118
µg/kg <1 <1
PCB-138
µg/kg <1 <1
PCB-153
µg/kg <1 <1
PCB-180
µg/kg <1 <1
Aldrin
µg/kg <1 <1
Dieldrin
µg/kg <1 <1
Endrin
µg/kg <1 <1
DDT
µg/kg 1,4 1,2
Lindane
µg/kg <1 <1
Octylphenol
µg/kg <5 <5
Nonyphenol
µg/kg 87 170
Pentachlorphenol
µg/kg <5 <5
TPH mg/kg
24
78
DEPH mg/kg
0,14
0,57
Mercury mg/kg
0,27
0,39
Arsenic mg/kg
14,4
17,2
Cadmium mg/kg
2,8
3,5
Lead mg/kg
68
78
Copper mg/kg
63
57
Zinc mg/kg
275
320
Chromium mg/kg
82
79
Nickel mg/kg
65
96
Total phosphorus
mg/kg
1248
1184
Organic nitrogen
mg/kg
2344
2233

UNDP/GEF DANUBE REGIONAL PROJECT

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ANNEX 1: Tables and Figures
page 18

Sample code

4-1061-L
4-1061-R
Components Unit
Concentration
Fluoranthene
µg/kg 114
93
Benzo(b)fluoranthene
µg/kg 343 236
Benzo(k)fluoranthene
µg/kg 168 122
Benzo(a)pyrene
µg/kg 242 146
Indeno(1,2,3 )pyrene
µg/kg 119
61
Benzo(g,h,i)perylene
µg/kg 57
30
PCB-28
µg/kg <1 <1
PCB-52
µg/kg <1 <1
PCB-101
µg/kg <1 <1
PCB-118
µg/kg <1 <1
PCB-138
µg/kg <1 <1
PCB-153
µg/kg <1 <1
PCB-180
µg/kg <1 <1
Aldrin
µg/kg
< 1
< 1
Dieldrin
µg/kg
< 1
< 1
Endrin
µg/kg
< 1
< 1
DDT
µg/kg 1,6 1,1
Lindane
µg/kg
< 1
< 1
Octylphenol
µg/kg <5 <5
Nonyphenol
µg/kg 53 260
Pentachlorphenol
µg/kg <5 <5
TPH mg/kg
41
22
DEPH mg/kg
0,3
0,27
Mercury mg/kg
0,30
0,36
Arsenic mg/kg
16,3
22,6
Cadmium mg/kg
3,0
3,5
Lead mg/kg
69
93
Copper mg/kg
64
60
Zinc mg/kg
286
320
Chromium mg/kg
78
127
Nickel mg/kg
68
147
Total phosphorus
mg/kg
1306
1245
Organic nitrogen
mg/kg
1676
1946

VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 19

Sample code

5-1040-L 5-1040-R
Components Unit
Concentration
Fluoranthene
µg/kg 84 54
Benzo(b)fluoranthene
µg/kg 90 89
Benzo(k)fluoranthene
µg/kg 50 47
Benzo(a)pyrene
µg/kg 59 57
Indeno(1,2,3 )pyrene
µg/kg 49 102
Benzo(g,h,i)perylene
µg/kg 24 49
PCB-28
µg/kg <1 <1
PCB-52
µg/kg <1 <1
PCB-101
µg/kg <1 <1
PCB-118
µg/kg <1 <1
PCB-138
µg/kg <1 <1
PCB-153
µg/kg <1 <1
PCB-180
µg/kg <1 <1
Aldrin
µg/kg
< 1
< 1
Dieldrin
µg/kg
< 1
< 1
Endrin
µg/kg
< 1
< 1
DDT
µg/kg 1 1,4
Lindane
µg/kg
< 1
< 1
Octylphenol
µg/kg <5 <5
Nonyphenol
µg/kg 60 120
Pentachlorphenol
µg/kg <5 <5
TPH mg/kg
29
23
DEPH mg/kg
0,29
0,46
Mercury mg/kg
0,21
0,31
Arsenic mg/kg
32,0
20,5
Cadmium mg/kg
2,9
3,4
Lead mg/kg
67
80
Copper mg/kg
377
64
Zinc mg/kg
279
326
Chromium mg/kg
60
94
Nickel mg/kg
59
104
Total phosphorus
mg/kg
1193
1283
Organic nitrogen
mg/kg
1431
2208
UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 20

Sample code

6-1022-L 6-1022-R
Components Unit
Concentration
Fluoranthene
µg/kg 39 60
Benzo(b)fluoranthene
µg/kg 57 98
Benzo(k)fluoranthene
µg/kg 36 62
Benzo(a)pyrene
µg/kg 39 65
Indeno(1,2,3 )pyrene
µg/kg 31 46
Benzo(g,h,i)perylene
µg/kg 11 17
PCB-28
µg/kg <1 <1
PCB-52
µg/kg <1 <1
PCB-101
µg/kg <1 <1
PCB-118
µg/kg <1 <1
PCB-138
µg/kg <1 <1
PCB-153
µg/kg <1 <1
PCB-180
µg/kg <1 <1
Aldrin
µg/kg <1 <1
Dieldrin
µg/kg <1 <1
Endrin
µg/kg <1 <1
DDT
µg/kg 1,6 1,2
Lindane
µg/kg <1 <1
Octylphenol
µg/kg <5 <5
Nonyphenol
µg/kg 48 93
Pentachlorphenol
µg/kg <5 <5
TPH mg/kg
34
25
DEPH mg/kg
0,11
0,16
Mercury mg/kg
0,17
0,28
Arsenic mg/kg
12,5
16,7
Cadmium mg/kg
2,3
3,0
Lead mg/kg
53
68
Copper mg/kg
70
71
Zinc mg/kg
211
290
Chromium mg/kg
60
81
Nickel mg/kg
55
75
Total phosphorus
mg/kg
1343
1245
Organic nitrogen
mg/kg
2313
2308
VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 21

Sample code

7-990-L
7-990-R
Components Unit
Concentration
Fluoranthene
µg/kg 77 112
Benzo(b)fluoranthene
µg/kg 301 359
Benzo(k)fluoranthene
µg/kg 150 173
Benzo(a)pyrene
µg/kg 198 243
Indeno(1,2,3 )pyrene
µg/kg 105 111
Benzo(g,h,i)perylene
µg/kg 50 53
PCB-28
µg/kg <1 <1
PCB-52
µg/kg <1 <1
PCB-101
µg/kg <1 <1
PCB-118
µg/kg <1 <1
PCB-138
µg/kg <1 <1
PCB-153
µg/kg <1 <1
PCB-180
µg/kg <1 <1
Aldrin
µg/kg
< 1
< 1
Dieldrin
µg/kg
< 1
< 1
Endrin
µg/kg
< 1
< 1
DDT
µg/kg 1,6 1,1
Lindane
µg/kg
< 1
< 1
Octylphenol
µg/kg <5 <5
Nonyphenol
µg/kg 57 90
Pentachlorphenol
µg/kg <5 <5
TPH mg/kg
15
6,4
DEPH mg/kg
0,28
0,53
Mercury mg/kg
0,27
0,32
Arsenic mg/kg
17,7
16,8
Cadmium mg/kg
2,7
3,1
Lead mg/kg
69
75
Copper mg/kg
75
79
Zinc mg/kg
293
316
Chromium mg/kg
75
109
Nickel mg/kg
91
104
Total phosphorus
mg/kg
1315
1219
Organic nitrogen
mg/kg
1972
1873
UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 22

Sample code

8-971 R
Components Unit
Concentration
Fluoranthene
µg/kg 72
Benzo(b)fluoranthene
µg/kg 355
Benzo(k)fluoranthene
µg/kg 165
Benzo(a)pyrene
µg/kg 226
Indeno(1,2,3 )pyrene
µg/kg 104
Benzo(g,h,i)perylene
µg/kg 47
PCB-28
µg/kg <1
PCB-52
µg/kg <1
PCB-101
µg/kg <1
PCB-118
µg/kg <1
PCB-138
µg/kg <1
PCB-153
µg/kg <1
PCB-180
µg/kg <1
Aldrin
µg/kg <
1
Dieldrin
µg/kg <
1
Endrin
µg/kg <
1
DDT
µg/kg 1,6
Lindane
µg/kg <
1
Octylphenol
µg/kg <5
Nonyphenol
µg/kg 150
Pentachlorphenol
µg/kg <5
TPH mg/kg
65
DEPH mg/kg
0,48
Mercury mg/kg
0,31
Arsenic mg/kg
18,4
Cadmium mg/kg
3,4
Lead mg/kg
76
Copper mg/kg
86
Zinc mg/kg
317
Chromium mg/kg
77
Nickel mg/kg
81
Total phosphorus
mg/kg
1384
Organic nitrogen
mg/kg
1863
VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 23

Sample code

9-956-L
9-956-R
Components Unit
Concentration
Fluoranthene
µg/kg 75 92
Benzo(b)fluoranthene
µg/kg 132 177
Benzo(k)fluoranthene
µg/kg 85 115
Benzo(a)pyrene
µg/kg 96 124
Indeno(1,2,3 )pyrene
µg/kg 69 96
Benzo(g,h,i)perylene
µg/kg 25 34
PCB-28
µg/kg <1 <1
PCB-52
µg/kg <1 <1
PCB-101
µg/kg <1 <1
PCB-118
µg/kg <1 <1
PCB-138
µg/kg <1 <1
PCB-153
µg/kg <1 <1
PCB-180
µg/kg <1 <1
Aldrin
µg/kg <1 <1
Dieldrin
µg/kg <1 <1
Endrin
µg/kg <1 <1
DDT
µg/kg 1,4 1,6
Lindane
µg/kg <1 <1
Octylphenol
µg/kg <5 <5
Nonyphenol
µg/kg 140 130
Pentachlorphenol
µg/kg <5 <5
TPH mg/kg
25
31
DEPH mg/kg
0,2
<0,1
Mercury mg/kg
0,27
0,35
Arsenic mg/kg
17,3
16,2
Cadmium mg/kg
3,2
3,3
Lead mg/kg
72
80
Copper mg/kg
75
86
Zinc mg/kg
315
334
Chromium mg/kg
103
87
Nickel mg/kg
94
98
Total phosphorus
mg/kg
1240
1163
Organic nitrogen
mg/kg
2229
1957

UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 24

Sample code

10-924-L 10-924-R
Components Unit
Concentration
Fluoranthene
µg/kg 35 63
Benzo(b)fluoranthene
µg/kg 52 115
Benzo(k)fluoranthene
µg/kg 29 74
Benzo(a)pyrene
µg/kg 40 95
Indeno(1,2,3 )pyrene
µg/kg 29 75
Benzo(g,h,i)perylene
µg/kg 13 29
PCB-28
µg/kg 1,2 <1
PCB-52
µg/kg <1 <1
PCB-101
µg/kg <1 <1
PCB-118
µg/kg <1 <1
PCB-138
µg/kg <1 <1
PCB-153
µg/kg <1 <1
PCB-180
µg/kg <1 <1
Aldrin
µg/kg <1 <1
Dieldrin
µg/kg <1 <1
Endrin
µg/kg <1 <1
DDT
µg/kg 1,2 1,3
Lindane
µg/kg <1 <1
Octylphenol
µg/kg <5 <5
Nonyphenol
µg/kg 98 110
Pentachlorphenol
µg/kg <5 <5
TPH mg/kg
40
<1
DEPH mg/kg
0,75
0,1
Mercury mg/kg
0,22
0,32
Arsenic mg/kg
10,6
13,4
Cadmium mg/kg
1,9
3,1
Lead mg/kg
49
71
Copper mg/kg
44
86
Zinc mg/kg
139
294
Chromium mg/kg
55
85
Nickel mg/kg
64
80
Total phosphorus
mg/kg
914
1156
Organic nitrogen
mg/kg
1524
2637
VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

---

Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 25

Sample code

1077-R
0-10 10-20 20-30 30-40 40-50 50-60
60-70 70-77
Core
cm
cm
cm
cm
cm
cm
cm
cm
Components Unit
Concentration
Fluoranthene
µg/kg 127 105 136 169 348 395 339 269
Benzo(b)fluoranthene
µg/kg 221 135 195 444 602 1075 605 756
Benzo(k)fluoranthene
µg/kg 129 81 120 287 324 553 323 390
Benzo(a)pyrene
µg/kg 166 90 137 317 429 746 429 521
Indeno(1,2,3 )pyrene
µg/kg 111 65 103 244 283 579 296 368
Benzo(g,h,i)perylene
µg/kg 39 23 35 84 93 188 94 116
PCB-28
µg/kg <1 <1 <1 <1 1,0 1,6 1,6 2,7
PCB-52
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
PCB-101
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
PCB-118
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
PCB-138
µg/kg <1 <1 <1 <1 1,3 1,2 1,4 1,7
PCB-153
µg/kg <1 <1 <1 <1 1,6 1,5 2,0 1,7
PCB-180
µg/kg <1 <1 <1 <1 1,7 2,0 1,8 1,7
Aldrin
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
Dieldrin
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
Endrin
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
DDT
µg/kg 1,1 <1 1,1 1,3 1,1 1,6 1,4 2,1
Lindane
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
Octylphenol
µg/kg <5 <5 <5 <5 <5 19 7,2 8,8
Nonyphenol
µg/kg 300 140 580 1600
4800 11000 5400
3600
Pentachlorphenol
µg/kg <5 <5 <5 <5 <5 <5 <5 <5
TPH
mg/kg 68 49 108 49 123 220 197 76
DEPH
mg/kg 0,47 0,27 0,45 0,49 0,74 0,84 0,47 0,56
Mercury
mg/kg 0,36 0,35 0,49 0,64 1,05 1,46 1,50 1,36
Arsenic
mg/kg 16,7 18,6 18,7 19,7 27,6 33,3 36,1 58,1
Cadmium
mg/kg 3,1 3,4 4,0 4,6 6,7 9,1 7,1 6,1
Lead
mg/kg 74 77 85 109 151 197 176 168
Copper
mg/kg 54 51 56 65 80 84 72 68
Zinc
mg/kg 292 309 349 446 619 727 682 589
Chromium
mg/kg 89 122 101 105 138 151 174 126
Nickel
mg/kg 105 121 106 104 116 113 133 110
Total
phosphorus
mg/kg 1149 1117 1245 1247 1453 1497 1505 1315
Organic
nitrogen
mg/kg 2065 1675 1952 1987 2301 2121 2165 2407

UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 26

Sample code

991-R
0-10 20-30 30-40 40-50 50-60 60-67
Core
cm
cm
cm
cm
cm
cm
Components Unit
Concentration
Fluoranthene
µg/kg 44 82 171 157 209 121
Benzo(b)fluoranthene
µg/kg 62 124 226 273 363 170
Benzo(k)fluoranthene
µg/kg 36 63 128
151
187 82
Benzo(a)pyrene
µg/kg 45 89 167 194 232 114
Indeno(1,2,3 )pyrene
µg/kg 52 93 212 202 146 115
Benzo(g,h,i)perylene
µg/kg 25 45 96 92 72 56
PCB-28
µg/kg <1 <1 <1 <1 <1 <1
PCB-52
µg/kg <1 <1 <1 <1 <1 <1
PCB-101
µg/kg <1 <1 <1 <1 <1 <1
PCB-118
µg/kg <1 <1 <1 <1 <1 <1
PCB-138
µg/kg <1 <1 <1 <1 <1 <1
PCB-153
µg/kg <1 <1 <1 <1 <1 <1
PCB-180
µg/kg <1 <1 <1 <1 <1 <1
Aldrin
µg/kg
< 1
< 1
< 1
< 1
< 1
< 1
Dieldrin
µg/kg
< 1
< 1
< 1
< 1
< 1
< 1
Endrin
µg/kg
< 1
< 1
< 1
< 1
< 1
< 1
DDT
µg/kg
< 1
< 1
1,1
1,2
1,9
< 1
Lindane
µg/kg
< 1
< 1
< 1
< 1
< 1
< 1
Octylphenol
µg/kg <5 <5 <5 <5 <5 <5
Nonyphenol
µg/kg 40 330 450 400 920 1300
Pentachlorphenol
µg/kg <5 <5 <5 <5 <5 <5
TPH
mg/kg 6,9 38 48 56 46 41
DEPH
mg/kg <0,1 0,24 0,55 0,37 0,37 0,41
Mercury
mg/kg 0,15 0,33 0,67 0,66 0,77 0,50
Arsenic
mg/kg 12,2 13,4 19,8 20,8 24,2 22,2
Cadmium
mg/kg 2,0 3,0 4,7 4,3 4,5 3,1
Lead mg/kg
45
70
121
125
128
80
Copper
mg/kg 54 83 137 143 157 123
Zinc
mg/kg 173 258 457 437 484 295
Chromium
mg/kg 110 107 125 106 119 117
Nickel
mg/kg 93 92 90 93 98 105
Total
phosphorus
mg/kg 935 1030 1318 1233 1220 1021
Organic
nitrogen
mg/kg 1011 1297 1977 1946 2040 983

VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

---

Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 27

Sample code

956-L
0-10 10-20 20-30 30-40 40-50 50-60 60-70 70-78
Core
cm
cm
cm
cm
cm
cm
cm
cm
Components Unit
Concentration
Fluoranthene
µg/kg 90 117 141 138 123 121 130 141
Benzo(b)fluoranthene
µg/kg 196 356 149 188 259 190 408 225
Benzo(k)fluoranthene
µg/kg 103 196 85 100 132 103 187 111
Benzo(a)pyrene
µg/kg 131 243 112 133 177 137 280 150
Indeno(1,2,3 )pyrene
µg/kg 121 222 110 173 196 126 235 212
Benzo(g,h,i)perylene
µg/kg 41 75 60 84 92 63 115 96
PCB-28
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
PCB-52
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
PCB-101
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
PCB-118
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
PCB-138
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
PCB-153
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
PCB-180
µg/kg <1 <1 <1 <1 <1 <1 <1 <1
Aldrin
µg/kg
<1
<1
<1
< 1
< 1
< 1
< 1
< 1
Dieldrin
µg/kg
<1
<1
<1
< 1
< 1
< 1
< 1
< 1
Endrin
µg/kg
<1
<1
<1
< 1
< 1
< 1
< 1
< 1
DDT
µg/kg 1,5 1,4 1,3 1,5 1,3 1,3 1,3 1,2
Lindane
µg/kg
<1
<1
<1
< 1
< 1
< 1
< 1
< 1
Octylphenol
µg/kg <5 <5 <5 <5 <5 <5 <5 <5
Nonyphenol
µg/kg 120 280 260 310 320 240 680 370
Pentachlorphenol
µg/kg <5 <5 <5 <5 <5 <5 <5 <5
TPH
mg/kg 52 49 22 36 54 76 58 31
DEPH
mg/kg 0,45 0,4 0,32 0,32 0,27 0,5 0,17 0,23
Mercury
mg/kg 0,33 0,40 0,46 0,46 0,60 0,57 0,69 0,65
Arsenic
mg/kg 18,8 18,4 19,9 19,1 21,3 21,7 23,2 19,7
Cadmium
mg/kg 3,5 3,5 3,9 4,0 4,5 3,9 4,7 4,8
Lead
mg/kg 80 90 103 95 112 113 123 115
Copper
mg/kg 82 87 97 99 113 115 136 122
Zinc
mg/kg 350 365 391 376 416 392 466 437
Chromium
mg/kg 103 97 117 102 100 122 117 97
Nickel
mg/kg 97 95 94 88 98 100 91 90
Total
phosphorus
mg/kg 1286 1582 1365 1470 1313 1332 1503 1387
Organic
nitrogen
mg/kg 2321 2309 2305 2274 1986 2318 2297 2306


UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 28
FIGURE 1. VERTICAL CONCENTRATION DISTRIBUTION OF
DIFFERENT COMPONENTS IN CORE SAMPLE 1077 R
Fluoranthene
Benzo(b)fluoranthene
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-77 cm
70-77 cm
0
50
100
150
200
250
300
350
400
(µg/kg)
0
100
200
300
400
500
600
700
800
900
1000 1100
(µg/kg)


Benzo(k)fluoranthene
Benzo(a)pyrene
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-77 cm
70-77 cm
0
50
100
150
200
250
300
350
400
450
500
550
600
0
50 100 150 200 250 300 350 400 450 500 550 600 650 700 750
(µg/kg)
(µg/kg)


Indeno(1,2,3)pyrene
Benzo(g,h,i)perylene
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-77 cm
70-77 cm
0
100
200
300
400
500
600
0
20
40
60
80
100
120
140
160
180
200
(µg/kg)
(µg/kg)





VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

---

Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 29
DDT
Nonyphenol
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-77 cm
70-77 cm
1
1,2
1,4
1,6
1,8
2
2,2
0
1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 11000
(µg/kg)
(µg/kg)


TPH
DEPH
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-77 cm
70-77 cm
0
50
100
150
200
250
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
(mg/kg)
(mg/kg)


Mercury
Arsenic
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-77 cm
70-77 cm
0
0,2
0,4
0,6
0,8
1
1,2
1,4
1,6
0
10
20
30
40
50
60
(mg/kg)
(mg/kg)


Cadmium
0-10 cm
10-20 cm
20-30 cm
30-40 cm
40-50 cm
50-60 cm
60-70 cm
70-77 cm
0
1
2
3
4
5
6
7
8
9
10
(mg/kg)

UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 30
Lead
Copper
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-77 cm
70-77 cm
0
20
40
60
80
100
120
140
160
180
200
0
20
40
60
80
100
120
140
160
180
(mg/kg)
(mg/kg)


Zinc
Chromium
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-77 cm
70-77 cm
0
50 100 150 200 250 300 350 400 450 500 550 600 650 700 750
0
20
40
60
80
100
120
140
160
180
(mg/kg)
(mg/kg)


Nickel
Total phosphorus
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-77 cm
70-77 cm
0
20
40
60
80
100
120
140
0
200
400
600
800
1000
1200
1400
1600
(mg/kg)
(mg/kg)


Organic nitrogen
0-10 cm
10-20 cm
20-30 cm
30-40 cm
40-50 cm
50-60 cm
60-70 cm
70-77 cm
0
500
1000
1500
2000
2500
(mg/kg)

VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

---

Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 31
FIGURE 2. VERTICAL CONCENTRATION DISTRIBUTION OF
DIFFERENT COMPONENTS IN CORE SAMPLE 991
Fluoranthene
Benzo(b)fluoranthene
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-67 cm
60-67 cm
0
50
100
150
200
250
300
350
400
0
100
200
300
400
500
600
700
800
900
1000 1100
(µg/kg)
(µg/kg)


Benzo(k)fluoranthene
Benzo(a)pyrene
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-67 cm
60-67 cm
0
50
100
150
200
250
300
350
400
450
500
550
600
0
50 100 150 200 250 300 350 400 450 500 550 600 650 700 750
(µg/kg)
(µg/kg)


Indeno(1,2,3)pyrene
Benzo(g,h,i)perylene
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-67 cm
60-67 cm
0
100
200
300
400
500
600
0
20
40
60
80
100
120
140
160
180
200
(µg/kg)
(µg/kg)



UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 32
DDT
Nonyphenol
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-67 cm
60-67 cm
1
1,2
1,4
1,6
1,8
2
2,2
0
200
400
600
800
1000
1200
1400
(µg/kg)
(µg/kg)


TPH
DEPH
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-67 cm
60-67 cm
0
50
100
150
200
250
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
(mg/kg)
(mg/kg)


Mercury
Arsenic
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-67 cm
60-67 cm
0
0,2
0,4
0,6
0,8
1
1,2
1,4
1,6
0
10
20
30
40
50
60
(mg/kg)
(mg/kg)


Cadmium
0-10 cm
10-20 cm
20-30 cm
30-40 cm
40-50 cm
50-60 cm
60-67 cm
0
1
2
3
4
5
6
7
8
9
10
(mg/kg)

VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

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Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 33
Lead
Copper
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-67 cm
60-67 cm
0
20
40
60
80
100
120
140
160
180
200
0
20
40
60
80
100
120
140
160
180
(mg/kg)
(mg/kg)


Zinc
Chromium
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-67 cm
60-67 cm
0
50 100 150 200 250 300 350 400 450 500 550 600 650 700 750
0
20
40
60
80
100
120
140
160
180
(mg/kg)
(mg/kg)


Nickel
Total phosphorus
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-67 cm
60-67 cm
0
20
40
60
80
100
120
140
0
200
400
600
800
1000
1200
1400
1600
(mg/kg)
(mg/kg)


Organic nitrogen
0-10 cm
10-20 cm
20-30 cm
30-40 cm
40-50 cm
50-60 cm
60-67 cm
0
500
1000
1500
2000
2500
(mg/kg)

UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 34
FIGURE 3. VERTICAL CONCENTRATION DISTRIBUTION OF
DIFFERENT COMPONENTS IN CORE SAMPLE 956
Fluoranthene
Benzo(b)fluoranthene
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-78 cm
70-78 cm
0
50
100
150
200
250
300
350
400
0
100
200
300
400
500
600
700
800
900
1000 1100
(µg/kg)
(µg/kg)


Benzo(k)fluoranthene
Benzo(a)pyrene
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-78 cm
70-78 cm
0
50
100
150
200
250
300
350
400
450
500
550
600
0
50 100 150 200 250 300 350 400 450 500 550 600 650 700 750
(µg/kg)
(µg/kg)


Indeno(1,2,3)pyrene
Benzo(g,h,i)perylene
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-78 cm
70-78 cm
0
100
200
300
400
500
600
0
20
40
60
80
100
120
140
160
180
200
(µg/kg)
(µg/kg)



VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

---

Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 35
DDT
Nonyphenol
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-78 cm
70-78 cm
1
1,2
1,4
1,6
1,8
2
2,2
0
200
400
600
800
1000
1200
1400
(µg/kg)
(µg/kg)


TPH
DEPH
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-78 cm
70-78 cm
0
50
100
150
200
250
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
(mg/kg)
(mg/kg)


Mercury
Arsenic
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-78 cm
70-78 cm
0
0,2
0,4
0,6
0,8
1
1,2
1,4
1,6
0
10
20
30
40
50
60
(mg/kg)
(mg/kg)


Cadmium
0-10 cm
10-20 cm
20-30 cm
30-40 cm
40-50 cm
50-60 cm
60-70 cm
70-78 cm
0
1
2
3
4
5
6
7
8
9
10
(mg/kg)

UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 36
Lead
Copper
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-78 cm
70-78 cm
0
20
40
60
80
100
120
140
160
180
200
0
20
40
60
80
100
120
140
160
180
(mg/kg)
(mg/kg)


Zinc
Chromium
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-78 cm
70-78 cm
0
50 100 150 200 250 300 350 400 450 500 550 600 650 700 750
0
20
40
60
80
100
120
140
160
180
(mg/kg)
(mg/kg)


Nickel
Total phosphorus
0-10 cm
0-10 cm
10-20 cm
10-20 cm
20-30 cm
20-30 cm
30-40 cm
30-40 cm
40-50 cm
40-50 cm
50-60 cm
50-60 cm
60-70 cm
60-70 cm
70-78 cm
70-78 cm
0
20
40
60
80
100
120
140
0
200
400
600
800
1000
1200
1400
1600
(mg/kg)
(mg/kg)


Organic nitrogen
0-10 cm
10-20 cm
20-30 cm
30-40 cm
40-50 cm
50-60 cm
60-70 cm
70-78 cm
0
500
1000
1500
2000
2500
(mg/kg)

VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

---

Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 37
FIGURE 4. PRACTICLE SIZE DISTRIBUTION OF SEDIMENT
SAMPLES

Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

1-1107 R-HU
0,1
0,0043
23,3

L-HU
0,040
0,0034
11,8




Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

2-1097 R-HU
0,041
0,0020
20,5

L-HU
0,090
0,0060
15,0


UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 38


Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

3-1072 R-HU
0,050
0,0016
31,3

L-HU
0,026
0,0015
17,3



Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

4-1061 R-HU
0,050
0,0012
41,7

L-HU
0,032
0,0014
22,9


VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

---

Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 39


Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

5-1040 R-HU
0,053
0,0015
35,3

L-HU
0,062
0,0048
12,9



Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

6-1022 R-HU
0,028
0,0026
10,8

L-HU
0,043
0,0037
11,6


UNDP/GEF DANUBE REGIONAL PROJECT

---

ANNEX 1: Tables and Figures
page 40


Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

7-990 R-HU
0,026
0,0010
26,0

L-HU
0,030
0,0010
30,0




Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

8-971 R-HU
0,064
< 0,0010 > 64,0

VITUKI/DR. BÉLA CSÁNYI, MS. MÁRIA BIHARI

---

Technical Assistance for Iron Gate Sediments Evaluation ­ Annexes
page 41


Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

9-956 R-HU
0,021
< 0,0010
> 21,0

L-HU
0,018
< 0,0010
> 18,0


Crude Tiny
Crude
Middle
Fine
Sandflour Silt Loam
Gravel Sand

grain size d(mm)
Sample code
D60
D10
U Marking

10-924 R-HU
0,061
< 0,0010 > 61,0
L-HU
0,046
0,0020
23,0



UNDP/GEF DANUBE REGIONAL PROJECT

---

---