ANNEX 3






Baseline Monitoring Results

PHASE II - period– June 2005




















HYDROCHEMICAL MONITORING




І Persina Nature Park

period – June 22 through June 23, 2005.












І Persina Nature Park


period – June 22 through June 23, 2005.


1. the Danube in the flooded wetlands area

Table І-1


No

Indicators

Unit

P o i n t s

ELV

Cathegory III




the Danube Fishermen settlement, Hisarlak locality (upstream of Persin Island and the town of Belene)

the Danube, Belene arm, opposite Persina 2 PS ”

the Danube, end of Belene arm, boundary of Persina Nature Park, after the end of Persin Island, upstream of the Svilosa plant, town of Svishtov

the Danube, the arm between Goliama Barzina and Persin Islands, near the Fishermen’s Hut

the Danube, at the mouth of Gardata drainage channel


1

Geographic coordinates


430 40.820’ N 250 06.060’ E

430 38.648’ N

250 12.975’ E

430 39.037’ N

250 17.552’ E

430 40.861’ N

250 12.710 ’E

430 39.824’ N

250 16.150’ E


2

Point No.


1

2

3

4

5


3

Protocols from RIEW Pleven – date of sampling

No./date

№431/04.07.05

sample taken 23.06. 2005

№421/04.07.05

sample taken 22.06. 2005

№433/04.07.05

sample taken 23.06.05

№418/04.07.05.

sample taken

22.06.05

№ 420/04.07.05

sample taken 22.06. 2005



Group A Common physical and inorganic chemical parameters

4

Temperature

0С

22,3

24,8

23,1

21,3

20,4


5

Active reaction pH

-

8,1

8,2

8,1

7,9

7,5

6-9

6

Turbidity

FAU

29

9

33

8

8


7

Dissolved O2

mg/dm3

3,03

3,46

3,32

2,9

1,1

< 2

8

Saturation with О2

mg/dm3

34,7

40

38,2

37,5

13,8

20

9

Electrical conductivity

mg/dm3

390

388

-

-

-

-

10

Suspended solids

mg/dm3

29

28

29

33

34

100

11

Fe / total iron

mg/dm3

0,135

-

-

-

-

5.0

12

Mn /total manganese

mg/dm3

<0.03

-

-

-


0.8

13

N-NH4 /ammonia nitrogen

mg/dm3

0,3

0,09

0,2

0,1

0,2

5.0

14

N-NО2 /nitrite nitrogen

mg/dm3

0,026

0,025

0,0240

0,083

0,008

0.06

15

N-NО3 /nitrate nitrogen

mg/dm3

0,7

<0,05

0,68

0,55

0,028

20

16

Keldahl nitrogen / N-NH4;+ N org

mg/dm3

1,4

0,7

0,7

0,7

1,4

15

17

N org /Organic nitrogen *

mg/dm3

-

-

-

-

-

10

18

Total nitrogen / Nt

mg/dm3

2,08

0,72

1,4

1,33

1,69

35.06

19

Soluble phosphates /such as PO4 /

mg/dm3

0,1

0,1

0,1

0,09

1,34

2

19.1

Soluble phosphates /such as P

mg/dm3

-

-

-

-

-

0.7

20

total phosphorus Рt / as PO4 /

mg/dm3

-

-

-

-

-

3

20.1

total phosphorus Рt / as P /

mg/dm3

0,09

0,08

0,09

0,07

0,6

1


Group B Common organic pollution indicators

21

oxidizing capacity

mg/dm3

7

1,9

2,6

5,4

32,3

40

22

COD

mg/dm3

11

5,3

5,7

10,6

48,6

100

23

BOD5

mg/dm3

3,8

1,7

2

3,5

16,2

25


Group C Indicators for inorganic substances from industrial enterprises

24

Cr+3 / tri-valent chromium

mg/dm3

Cr total <0,05

-

-

-

-

1.0

25

Cr+6 / six-valent chromium ***

mg/dm3


-

-

-

-

0.1

26

Cu / copper***

mg/dm3

<0,03

-

-

-


0.5

27

Co / cobalt***

mg/dm3

<0,05

-

-

-

-

0.5

28

Zn / zinc***

mg/dm3

<0,02

-

-

-

-

10

29

Ni / nickel***

mg/dm3

<0,05

-

-

-

-

0.5

30

Cd / cadmium***

mg/dm3

0,0018+_0,0001

-

-

-

-

0.05

31

Pb / lead***

mg/dm3

<0,05

-

-

-

-

0.2

32

As / arsenic***

mg/dm3

0,0031+_0,0005

-

-

-

-



Group C Indicators for organic substances from industrial enterprises

33

petroleum products

mg/dm3

2,9

-

-

-

-

0.5

34

Total extractable

mg/dm3

3,3

-

-

-

-

5.0

N org / Орг.nitrogen * - applies to Group B

Cr t- chromium total **


Protokol №340/16.05.2005г. -RIEW W.Tarnowo ***


** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986


All indicators are proving that waters are corresponding to Cathegory III - (except the value is petroleum products 2,9 )








І-2. Martvo marsh and Pischensko marsh - Table I-2



No



Indicators



Unit

P o i n t s

ELV

Cathegory III




Persin Island, Martvoto marsh, the middle from the southern coast

Persin Island, Pischensko marsh, southern coast (the location closest to the road)


1

Geographic coordinates


430 40.407’ N

250 14,086’ E

430 40.177’ N

250 2.522 ’ E

-

2

Point No.

-

6

7

-

3

Protocols from RIEW Pleven – date of sampling

No./date

417/04.07.05 sample taken on

22.06.05

415/04.07.05 sample taken on

22.06.05

-


Group A Common physical and inorganic parameters

4

Temperature

0С

23

24,3


5

Turbidity

FAU

15

8


6

рН

-

7,45

7,45

6-9

7

Dissolved O2

mg/dm3

2,02

-

< 2

8

Saturation with О2

%

21

-

20

9

Electrical conductivity

MS/cm2

-

-

-

10

Suspended solids

mg/dm3

35

28

100

11

Dissolved substances

mg/dm3

-

-

1500

14

Total dry residue

mg/dm3

575

900,9

-

15

N-NH4 /ammonia nitrogen

mg/dm3

0,2

0,2

5.0

16

N-NО2 /nitrite nitrogen

mg/dm3

0,006

0,005

0.06

17

N-NО3 /nitrate nitrogen

mg/dm3

0,09

0,14

20

18

Keldahl nitrogen / N-NH4;+ N org

mg/dm3

1,4

1,4

15

19

N org /Organic nitrogen *

mg/dm3

-

-

10

20

Total nitrogen / Nt

mg/dm3

1,50

1,55

35.06

21

Soluble phosphates /such as PO4 /

mg/dm3

0,07

0,02

2

21.1

Soluble phosphates /such as P

mg/dm3

-

-

0.7

22

total phosphorus Рt / as PO4 /

mg/dm3

-

-

3

22.1

total phosphorus Рt / as P /

mg/dm3

0,08

0,06

1


Group B Common organic pollution indicators

23

oxidizing capacity

mg/dm3

27,8

30,7

40

24

COD

mg/dm3

40

47,6

100

25

BOD5

mg/dm3

13.5

16,1

25

N org / Орг.nitrogen * - applies to Group B

Cr t- chromium total **


Protokol №340/16.05.2005г. -RIEW W.Tarnowo ***


** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986

All indicators are proving that waters are corresponding to Cathegory III


Sediments




No



Indicators



Unit

P o i n t s




Persin Island, Martvoto marsh,

Persin Island, Pischensko marsh,

1

Geographic coordinates



430 40.407’ N

250 14,086’ E

430 40.177’ N

250 2,522’ E

2

Point No.

-

6

7

3

Protocols from RIEW Plewen – RIEW V.Tarnowo* – date of sampling

No./date

424-С/15.09.05 sample taken

22.06.05

425-С/15.09.05 sample taken

22.06.05

4

рН**

-

7,7

7,8

5

Total dry residue**

%

4,8

0,4

6

Corg.**

g/kg

67,6

4,11

7

Fe / total iron*

mg/kg

25440+3800

4060+600

8

Mn /total manganese/*

mg/kg

259+41

122+20

9

Cr chromium total *

mg/kg

43,8+11

4,1+1,0

10

Cu / copper*

mg/kg

51,0+3,8

4,3+0,3

11

Co / cobalt*

mg/kg

11,9+1,8

2,1+0,3

12

Zn / zinc*

mg/kg

133+14,0

22,7+2,4

13

Ni / nickel*

mg/kg

65,2+12,3

7,2+1,4

14

Cd / cadmium*

mg/kg

0,53+0,10

<0,2

15

Pb / lead*

mg/kg

47,7+8,10

62,7+1,1,4

16

As/arsenic*

mg/kg

8,5+1,3

1,3+0,2

I-3 Drainage channels

Table І-3




No




Indicators




Unit

P o i n t s




Gardata drainage channel

Persin Island, drainage channel near Persin PS 2

Persin Island, drainage channel near Persin PS 1

Main drainage channel near the town of Belene, near Belene PS 1

drainage channel near Kaikusha Protected Area

ELV
cathegory

III

1

Geographic coordinates


430 39.782’ N

250 16.150’ E

430 38.801’ N

250 12.867’ E

430 39.402’ N

250 08.245’ E

430 39.782’ N

250 16.150’ E

430 35.742’ N

250 12.377’ E


2

Point No. 13

No./date

5А

8

9

11

13А


3

Protocols from RIEW Pleven – date of sampling

No./date

419/04.07.2005г. sample taken on 22.06.2005г.

422/04.07.2005г.

sample taken on 22.06. 2005г.

423/04 07.2005 г.

sample taken on 22.06.2005г.

432/ 04.07.2005г.

sample taken on 23.06.2005г.

434/04.07.2005 г. sample taken on 23.06.2005г..


Group A Common physical and inorganic parameters

4

Temperature

0С

21,5

22

22,9

23

23,1


5

рН


7,6

7,7

7,85

7,7

8,15

6-9

6

Turbidity

FAU

18

18

10

10

-


7

Dissolved O2

mg/dm3

1,69

1,82

3,53

1,49

2,62

< 2

8

Saturation with О2

%

17

22,3

43,2

17,6

32,1

20

9

Electrical conductivity

MS/cm2

-

-

-

-

-

-

10

Suspended solids

mg/dm3

33

38

31

34

46

100

11

Fe / total iron

mg/dm3

-

-

-

-

-

5.0

12

Mn /total manganese

mg/dm3

-

-

-

-

-

0.8

13

N-NH4 /ammonia nitrogen

mg/dm3

0,2

0,4

0,2

0,4

1,5

5.0

14

N-NО2 /nitrite nitrogen

mg/dm3

0,005

0,008

0,026

0,017

0,039

0.06

15

N-NО3 /nitrate nitrogen

mg/dm3

0,08

0,05

<0,05

0,19

0,49

20

16

Keldahl nitrogen / N-NH4;+ N org

mg/dm3

0,7

1,4

1,4

1,4

2,8

15

17

N org /Organic nitrogen *

mg/dm3

-

-

-

-

-

10

18

Total nitrogen / Nt *

mg/dm3

0,78

1,46

1,43

1,61

3,33

35.06

19

Soluble phosphates /such as PO4 /

mg/dm3

1,03

0,3

0,2

0,2

0,4

2

20

Soluble phosphates /such as P

mg/dm3

-

-

-

-

-

0.7

21

total phosphorus Рt / as PO4 /

mg/dm3






3

22

total phosphorus Рt / as P /

mg/dm3

0,4

0,2

0,1

0,1

0,2

1

Group B Common organic pollution indicators

23

oxidizing capacity

mg/dm3

30,4

9,3

8,0

6,7

17,3

40

24

COD

mg/dm3

51,2

15,6

12,5

12,5

27,9

100

25

BOD5

mg/dm3

16,8

5,2

4,3

4

9,1

25

N org / Орг.nitrogen * - applies to Group B


** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986


All indicators are proving that waters are corresponding to Cathegory III





























I-4 Town waste water collector for the town of Belene

Table І-4


No


Indicators


Unit

Point – the town of Belene’s waste water collector


Cathegory III

Regulation 6/ 2000 on emission standards

1

2

3

4

5


1

Geographic coordinates


430 38.716’ N

250 08.571’ E

-


2

Point No.

-

10



3

Protocols from RIEW Pleven – date of sampling

No./date

435/04.07.2005 г.

sample taken on 23.06.2005г.

-


Group A Common physical and inorganic parameters

4

Temperature

0С

17



5

рН

-

7,6

6-9

6-9

6

Electrical conductivity

MS/cm2

1082



7

Suspended solids

mg/dm3

56

100

35

8

Dissolved substances

mg/dm3

-

1500

-

9

Total dry residue

mg/dm3

-

1600

-

10

N-NH4 /ammonia nitrogen

mg/dm3

31,6

5.0

-

11

N-NО2 /nitrite nitrogen

mg/dm3

0,057

0.06

-

12

N-NО3 /nitrate nitrogen

mg/dm3

0,48

20

-

13

Keldahl nitrogen / N-NH4;+ N орг

mg/dm3

35

15

-

14

N org /Organic nitrogen *

mg/dm3

-

10

-

15

Total nitrogen / Nt *

mg/dm3

35,54

35.06

15

16

Soluble phosphates /such as PO4 /

mg/dm3

8,6

2

-

15.1

Soluble phosphates /such as P /

mg/dm3

-

0.7

-

16

total phosphorus Рt / as PO4 /

mg/dm3

5,8

3

-

16.1

total phosphorus Рt / as P /

mg/dm3

-

1

2

Group B Common organic pollution indicators

17

oxidizing capacity

mg/dm3

119,7

40

-

18

COD

mg/dm3

206,7

100

-

19

BOD5

mg/dm3

100

25

-

20

petroleum products

mg/dm3

7,4

0.5

-

Group C Indicators for organic substances from industrial enterprises

21

Total extractable substances

mg/dm3

8.4

5

-

22

detergenti

mg/dm3

6,2



Group C Indicators for inorganic substances from industrial enterprises

23

Cr chromium total ***

mg/dm3

<0,05



24

Cu / copper***

mg/dm3

<0.03

0,5


25

Co / cobalt***

mg/dm3

<0,05

0,5


26

Zn / zinc***

mg/dm3

0,050+0,006

10


27

Ni / nickel***

mg/dm3

<0.05

0,5


28

Cd / cadmium***

mg/dm3

0.0023+0,0002

0,05


29

Pb / lead***

mg/dm3

<0,05

0,2



N org / Орг.nitrogen * - applies to Group B

Cr t- chromium total **

Protokol №340/16.05.2005г. -RIEW W.Tarnowo ***

* indicators for “sensitive zone”

** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986

*** Regulation № 6 /09.11.2000 on the emission levels for admissible content of harmful and hazardous substances in waste water discharged info the water bodies SG 97/2000 г.


The wasted waters are strongly polluated with high concentration of: BOD5 , COD, Amonia and Organic nitrogen and Total Phosphorus,total extractable substances, petroleum products.















І-5. Piesometer at Pischensko marsh – Ground water

Table І-5



No

Indicators


Unit

Point – Piesometer near Pischensko marsh

PM1

ELV

Regulation 1/2000





ET

PT

1

Geographic coordinates

grad

430 39.990’ N

250 12.951’ E

-


2

Point No.

-

14



3

Protocols from RIEW Pleven – date of sampling

No./date

416/04.07.2005 г.

sample taken on 22.06.2005 г.

-


4

Temperature

0С

20,3



5

рН

-

7,4



6

Dissolved oxygen

mg/dm3

2,22



7

Saturation with О2

%

24,4



8

Suspended solids

mg/dm3

31



9

Dissolved substances

mg/dm3

1014



10

Total dry residue

mg/dm3

1045



11

Electrical conductivity

MS/cm2

1116



12

N-NH4 /ammonia nitrogen

mg/dm3

0,2

0.12

1.2

13

N-NО2 /nitrite nitrogen

mg/dm3

1,364

0.025

0.125

14

N-NО3 /nitrate nitrogen

mg/dm3

0,16

10

30

15

Soluble phosphates /such as PO4 /

mg/dm3

0.09

0.1

1.0

16

total phosphorus / as P /

mg/dm3

-



17

alkalinity

mg/dm3

9



18

Chlorides Cl /

mg/dm3

52,7

30

100

19

Sulphates SO4//

mg/dm3

58,2

50

150

20

Calcium Ca 2+

mg/dm3

157,2



21

Magnesium Mg 2+

mg/dm3

59,8



22

Carbonates CO3//

mg/dm3

<5



23

Hydrocarbonates HCO3/

mg/dm3

549



24

Total extractable substances

mg/dm3

1,6



25

Mn /total manganese

mg/dm3

0,90+0,14

0.02

0.05

26

Cu / copper***

mg/dm3

<0,03

0.03

0.1

27

Zn / zinc***

mg/dm3

0,054+0,006

0.2

1.0

28

Pb / lead***

mg/dm3

<0,05

0.03

0.2

29

Na

mg/dm3

23,3+1,8

50

100

30

K

mg/dm3

1,5+0,1




* Regulation №1 of the MOEW, MRDPW,MH and MI dated 07.07.2000 on the studying of the use and conservation of grund water, SG 57/ 2000

** ЕT – ecological threshold

*** PT – pollution threshold

The ground waters are with:

- N-NH4 /ammonia nitrogen - over ET – 1.67 times

- N-NO2 /nitrite nitrogen – over PT – 10.9 times

-Mn - over PT – 18 times

- Chlorides Cl - over ET-1.76 times

- Sulphates SO4//– over ЕT 1,16 times, 39% of PT

12