“Wetland Restoration and Pollution Reduction” GEF TF 050706
REPORT
Hydrochemical and hydrobiological local monitoring of water, soils and sediments of the two project areas – Persina Nature Park and Kalimok-Brushlen Protected Area – perior to the restoration work
BASELINE MONITORING RESULTS
PHASE II PERIOD 2005
A N N E X 2
BASELINE MONITORING RESULTS
PHASE II - period – April through Septemember 2005.
HYDROCHEMICAL AND HYDROBIOLOGICAL LOCAL MONITORING
PERIOD 2005
ANNEX 2.1
Baseline Monitoring Results
PHASE II - period–April 2005
HYDROCHEMICAL MONITORING
ANNEX 2.1.1
HYDROCHEMICAL MONITORING
І Persina Nature Park
period – April 19 through April 29, 2005.
І Persina Nature Park
period – April 19 through April 29, 2005.
1. the Danube in the flooded wetlands area
Table IІ-1
|
No |
Indicators |
Unit |
P o i n t s |
ELV Cathegory III |
|||||
|
|
|
|
the Danube Fishermen settlement, Hisarlak locality (upstream of Persin Island and the town of Belene) |
the Danube, Belene arm, opposite Persina 2 PS ” |
the Danube, end of Belene arm, boundary of Persina Nature Park, after the end of Persin Island, upstream of the Svilosa plant, town of Svishtov |
the Danube, the arm between Goliama Barzina and Persin Islands, near the Fishermen’s Hut |
the Danube, at the mouth of Gardata drainage channel |
|
|
|
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
9 |
|
|
1 |
Geographic coordinates |
grad |
430 40.820’ N 250 06.060’ E |
430 38.648’ N 250 12.975’ E |
430 39.037’ N 250 17.552’ E |
430 40.861’ N 250 12.710 ’E |
430 39.824’ N 250 16.150’ E |
|
|
|
3 |
Protocols from RIEW Pleven – date of sampling |
No./date |
No. 244/18.05.2005 sample taken 20.04. 2005 |
No. 240/29.04.05 sample taken 19.04. 2005 |
No. 246/29.04.2005sample taken 20.04. 2005 |
No. 237/29.04. 05 sample taken 19.04. 2005 |
No. 239/29.04.05 sample taken 19.04. 2005 |
|
|
|
|
Group A Common physical and inorganic chemical parameters |
||||||||
|
4 |
Temperature |
0С |
12.5 |
12.9 |
15.3 |
12.2 |
12.2 |
|
|
|
5 |
Active reaction pH |
- |
7.7 |
7.65 |
7.7 |
7.6 |
7.8 |
6-9 |
|
|
6 |
Dissolved O2 |
mg/dm3 |
4.07 |
3.75 |
3.56 |
3.59 |
3.88 |
> 2 |
|
|
7 |
Saturation with О2 |
% |
40.1 |
34.6 |
38.2 |
35.3 |
40.7 |
20 |
|
|
8 |
Electrical conductivity |
MS/cm2 |
373 |
370 |
- |
- |
- |
- |
|
|
9 |
Suspended solids |
mg/dm3 |
25 |
29 |
28 |
27 |
25 |
100 |
|
|
10 |
Fe / total iron |
mg/dm3 |
<0.05 |
- |
- |
- |
- |
5.0 |
|
|
11 |
Mn /total manganese |
mg/dm3 |
<0.01 |
- |
- |
- |
- |
0.8 |
|
|
12 |
N-NH4 /ammonia nitrogen |
mg/dm3 |
0.2 |
0.1 |
0.2 |
0.1 |
0.1 |
5.0 |
|
|
13 |
N-NО2 /nitrite nitrogen |
mg/dm3 |
0.026 |
0.020 |
0.025 |
0.015 |
0.019 |
0.06 |
|
|
14 |
N-NО3 /nitrate nitrogen |
mg/dm3 |
0.3 |
0.3 |
0.1 |
0.6 |
0.4 |
20 |
|
|
15 |
Keldahl nitrogen / N-NH4;+ N org |
mg/dm3 |
0.7 |
0.7 |
0.7 |
0.7 |
0.7 |
15 |
|
|
16 |
N org /Organic nitrogen * |
mg/dm3 |
0.5 |
0.6 |
0.5 |
0.6 |
0.6 |
10 |
|
|
17 |
Total nitrogen / Nt |
mg/dm3 |
1.03 |
1.02 |
0.82 |
1.32 |
1.12 |
35.06 |
|
|
18 |
Soluble phosphates /such as PO4 / |
mg/dm3 |
0.2 |
0.1 |
0.1 |
0.2 |
0.07 |
2 |
|
|
18.1 |
Soluble phosphates /such as P |
mg/dm3 |
|
|
|
|
|
0,7 |
|
|
19 |
total phosphorus Рt / as PO4 / |
mg/dm3 |
|
|
|
|
|
3,0 |
|
|
19.1 |
total phosphorus Рt / as P / |
mg/dm3 |
0.1 |
0.05 |
0.06 |
0.1 |
0.06 |
1 |
|
|
|
Group B Common organic pollution indicators |
||||||||
|
20 |
oxidizing capacity |
mg/dm3 |
5.4 |
3.8 |
5.4 |
8.3 |
5.5 |
40 |
|
|
21 |
COD |
mg/dm3 |
7.0 |
5.5 |
9.2 |
13.6 |
7.8 |
100 |
|
|
22 |
BOD5 |
mg/dm3 |
2.5 |
1.3 |
3.0 |
4.0 |
2.3 |
25 |
|
|
|
Group C Indicators for inorganic substances from industrial enterprises |
||||||||
|
23 |
Cr+3 / tri-valent chromium |
mg/dm3 |
<0.01** |
- |
- |
- |
- |
1.0 |
|
|
24 |
Cr+6 / six-valent chromium *** |
mg/dm3 |
|
- |
- |
- |
- |
0.1 |
|
|
25 |
Cu / copper*** |
mg/dm3 |
<0.01 |
- |
- |
- |
- |
0.5 |
|
|
26 |
Co / cobalt*** |
mg/dm3 |
<0.01 |
- |
- |
- |
- |
0.5 |
|
|
27 |
Zn / zinc*** |
mg/dm3 |
<0.01 |
- |
- |
- |
- |
10 |
|
|
28 |
Ni / nickel*** |
mg/dm3 |
<0.01 |
- |
- |
- |
- |
0.5 |
|
|
29 |
Cd / cadmium*** |
mg/dm3 |
0.019 |
- |
- |
- |
- |
0.05 |
|
|
30 |
Pb / lead*** |
mg/dm3 |
<0.01 |
- |
- |
- |
- |
0.2 |
|
|
31 |
As / arsenic*** |
mg/dm3 |
0.0017 |
|
|
|
|
|
|
|
|
Group C Indicators for organic substances from industrial enterprises |
||||||||
|
32 |
petroleum products |
mg/dm3 |
5.2 |
- |
- |
- |
- |
0.5 |
|
|
33 |
Total extractable |
mg/dm3 |
11.9 |
- |
- |
- |
- |
5.0 |
|
N org / Орг.nitrogen * - applies to Group B
Cr t- chromium total **
Protokol №340/16.05.2005г. -RIEW W.Tarnowo ***
** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986
All indicators are proving that waters are corresponding to Cathegory III - (except the value is petroleum products 5,2, total extractable-11,9)
І-2. Martvo marsh and Pischensko marsh
Table II-2
|
No |
Indicators |
Unit |
P o i n t s |
ELV Cathegory III |
|
|
|
|
|
Persin Island, Martvoto marsh, the middle from the southern coast |
Persin Island, Pischensko marsh, southern coast (the location closest to the road) |
|
|
1 |
2 |
3 |
4 |
5 |
8 |
|
1 |
Geographic coordinates |
|
430 40.407’ N 250 14,086’ E |
430 40.177’ N 250 2.522 ’ E |
- |
|
2 |
Point No. |
- |
6 |
7 |
- |
|
3 |
Protocols from RIEW Pleven – date of sampling |
No./date |
236/29.04.2005 sample taken on 19.04.2005 |
234/29.04.2005 sample taken on 19.04.2005 |
- |
|
|
Group A Common physical and inorganic parameters |
||||
|
4 |
Temperature |
0С |
13.3 |
13.2 |
|
|
5 |
рН |
- |
7.5 |
7.7 |
6-9 |
|
6 |
Dissolved O2 |
mg/dm3 |
1.24 |
2.8 |
< 2 |
|
7 |
Saturation with О2 |
% |
11 |
26.8 |
20 |
|
8 |
Electrical conductivity |
MS/cm2 |
- |
- |
- |
|
9 |
Suspended solids |
mg/dm3 |
31 |
29 |
100 |
|
10 |
Dissolved substances |
mg/dm3 |
812 |
1268 |
1500 |
|
11 |
Total dry residue |
mg/dm3 |
842 |
1297 |
- |
|
12 |
Fe / total iron |
mg/dm3 |
- |
- |
5.0 |
|
13 |
Mn /total manganese |
mg/dm3 |
- |
- |
0,8 |
|
14 |
N-NH4 /ammonia nitrogen |
mg/dm3 |
0.2 |
0.3 |
5.0 |
|
15 |
N-NО2 /nitrite nitrogen |
mg/dm3 |
0.006 |
0.005 |
0.06 |
|
16 |
N-NО3 /nitrate nitrogen |
mg/dm3 |
0.07 |
<0.05 |
20 |
|
17 |
Keldahl nitrogen / N-NH4;+ N org |
mg/dm3 |
0.7 |
0.7 |
15 |
|
18 |
N org /Organic nitrogen * |
mg/dm3 |
0.5 |
0.4 |
10 |
|
19 |
Total nitrogen / Nt |
mg/dm3 |
0.78 |
0.70 |
35.06 |
|
20 |
Soluble phosphates /such as PO4 / |
mg/dm3 |
0.2 |
0.07 |
2 |
|
20.1 |
Soluble phosphates /such as P |
mg/dm3 |
0,07 |
0,023 |
0.7 |
|
21 |
total phosphorus Рt / as PO4 / |
mg/dm3 |
0,3 |
0,15 |
3 |
|
21.1 |
total phosphorus Рt / as P / |
mg/dm3 |
0.1 |
0.05 |
1 |
|
|
Group B Common organic pollution indicators |
||||
|
22 |
oxidizing capacity |
mg/dm3 |
27.8 |
28.5 |
40 |
|
23 |
COD |
mg/dm3 |
34.4 |
44.3 |
100 |
|
24 |
BOD5 |
mg/dm3 |
10.9 |
14.8 |
25 |
N org / Орг.nitrogen * - applies to Group B
Cr t- chromium total **
Protokol №340/16.05.2005г. -RIEW W.Tarnowo ***
** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986
All indicators are proving that waters are corresponding to Cathegory III
Sediments – 234-C/27.05.2005 - sample 5 taken on 19.04.2005
|
No |
Indicators |
Unit |
P o i n t s |
|
|
|
|
|
Persin Island, Martvoto marsh, |
Persin Island, Pischensko marsh, |
|
1 |
Geographic coordinates |
|
430 40.407’ N 250 14,086’ E |
430 40.177’ N 250 0.2,522’ E |
|
2 |
Point No. |
- |
6 |
7 |
|
3 |
Protocols from RIEW Plewen – RIEW V.Tarnowo* – date of sampling |
No./date |
23-C/27.04.2005 sample taken on 19.04.2005 |
234-C /27.04.2005 sample taken on 19.04.2005 |
|
4 |
рН** |
- |
7.855 |
8.5 |
|
5 |
Total dry residue** |
% |
5.15 |
0.27 |
|
6 |
Corg.** |
g/kg |
52.1 |
3.96 |
|
7 |
Fe / total iron* |
mg/kg |
28200 |
3500 |
|
8 |
Mn /total manganese/* |
mg/kg |
357 |
121- |
|
9 |
Cr chromium total * |
mg/kg |
65.8 |
9.1 |
|
10 |
Cu / copper* |
mg/kg |
58.6 |
3.5 |
|
11 |
Co / cobalt* |
mg/kg |
14.0 |
<2 |
|
12 |
Zn / zinc* |
mg/kg |
144 |
16.3 |
|
13 |
Ni / nickel* |
mg/kg |
69.0 |
3.7 |
|
14 |
Cd / cadmium* |
mg/kg |
0.49 |
<0.2 |
|
15 |
Pb / lead* |
mg/kg |
50.8 |
<2 |
|
16 |
As/arsenic* |
mg/kg |
11.0 |
1.1 |
II-3 Drainage channels
Table IІ-3
|
No |
Indicators |
Unit |
P o i n t s |
|||||
|
|
|
|
Gardata drainage channel |
Persin Island, drainage channel near Persin PS 2 |
Persin Island, drainage channel near Persin PS 1 |
Main drainage channel near the town of Belene, near Belene PS 1 |
drainage channel near Kaikusha Protected Area |
ELV |
|
1 |
Geographic coordinates |
|
430 39.782’ N 250 16.150’ E |
430 38.801’ N 250 12.867’ E |
430 39.402’ N 250 08.245’ E |
430 39.782’ N 250 16.150’ E |
430 35.742’ N 250 12.377’ E |
|
|
2 |
Point No. 13 |
No./date |
5А |
8 |
9 |
11 |
13А |
|
|
3 |
Protocols from RIEW Pleven – date of sampling |
No./date |
238/ 29. 04.2005. sample taken on 19.04. 2005. |
241 / 29. 04.2005. sample taken on 19.04. 2005. |
242 / 29. 04. 2005 sample taken 19.04. 2005. |
245/ 29. 04.2005 sample taken 20.04. 2005. |
247/ 29. 0.4.2005 sample taken 20.04 2005. |
|
|
Group A Common physical and inorganic parameters |
||||||||
|
4 |
Temperature |
0С |
12.6 |
12.3 |
12.6 |
13.5 |
13.5 |
|
|
5 |
рН |
|
7.75 |
7.45 |
7.6 |
7.5 |
8.0 |
6-9 |
|
6 |
Dissolved O2 |
mg/dm3 |
3.77 |
3.15 |
3.61 |
3.22 |
3.9 |
> 2 |
|
7 |
Saturation with О2 |
% |
35.6 |
37.1 |
28.7 |
30.2 |
39.5 |
20 |
|
8 |
Electrical conductivity |
MS/cm2 |
- |
- |
- |
- |
- |
- |
|
9 |
Suspended solids |
mg/dm3 |
29 |
31 |
30 |
32 |
32 |
100 |
|
10 |
Fe / total iron |
mg/dm3 |
- |
- |
- |
- |
- |
5.0 |
|
11 |
Mn /total manganese |
mg/dm3 |
- |
- |
- |
- |
- |
0.8 |
|
12 |
N-NH4 /ammonia nitrogen |
mg/dm3 |
0.1 |
0.2 |
0.2 |
0.2 |
0.2 |
5.0 |
|
13 |
N-NО2 /nitrite nitrogen |
mg/dm3 |
0.02 |
0.013 |
0.021 |
0.01 |
0.026 |
0.06 |
|
14 |
N-NО3 /nitrate nitrogen |
mg/dm3 |
0.6 |
0.2 |
0.4 |
0.1 |
2.3 |
20 |
|
15 |
Keldahl nitrogen / N-NH4;+ N org |
mg/dm3 |
0.7 |
0.7 |
0.7 |
0.7 |
0.7 |
15 |
|
16 |
N org /Organic nitrogen * |
mg/dm3 |
0.6 |
0.5 |
0.5 |
0.5 |
0.5 |
10 |
|
17 |
Total nitrogen / Nt * |
mg/dm3 |
1.32 |
0.91 |
1.12 |
0.81 |
3.03 |
35.06 |
|
18 |
Soluble phosphates /such as PO4 / |
mg/dm3 |
0.08 |
0.06 |
0.09 |
0.2 |
0.9 |
2 |
|
19 |
Soluble phosphates /such as P |
mg/dm3 |
0,027 |
0,02 |
0,03 |
0.07- |
0,3 |
0.7 |
|
20 |
total phosphorus Рt / as PO4 / |
mg/dm3 |
0,15 |
0,21 |
0,12 |
0,2 |
0,9 |
3 |
|
21 |
total phosphorus Рt / as P / |
mg/dm3 |
0.05 |
0.07 |
0.04 |
0.1 |
0.3 |
1 |
|
Group B Common organic pollution indicators |
||||||||
|
22 |
oxidizing capacity |
mg/dm3 |
4.8 |
24.3 |
1.0 |
9.9 |
8.3 |
40 |
|
23 |
COD |
mg/dm3 |
7.8 |
36.4 |
<5 |
17.2 |
14.4 |
100 |
|
24 |
BOD5 |
mg/dm3 |
2.2 |
11.8 |
0.8 |
5.5 |
4.8 |
25 |
N org / Орг.nitrogen * - applies to Group B
** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986
All indicators are proving that waters are corresponding to Cathegory III
II-4 Town waste water collector for the town of Belene
Table IІ-4
|
No |
Indicators |
Unit |
Point – the town of Belene’s waste water collector |
Cathegory III |
Regulation 6/ 2000 on emission standards |
|
1 |
2 |
3 |
4 |
5 |
|
|
1 |
Geographic coordinates |
grad |
430 38.716’ N 250 08.571’ E |
- |
|
|
2 |
Point No. |
- |
10 |
|
|
|
3 |
Protocols from RIEW Pleven – date of sampling |
No./date |
248 / 18. 05.2005 г. sample taken on 20.04.2005 |
- |
|
|
Group A Common physical and inorganic parameters |
|||||
|
4 |
Temperature |
0С |
12.1 |
|
|
|
5 |
рН |
- |
7.55 |
6-9 |
6-9 |
|
6 |
Suspended solids |
mg/dm3 |
84 |
100 |
35 |
|
7 |
Dissolved substances |
mg/dm3 |
- |
1500 |
- |
|
8 |
Total dry residue |
mg/dm3 |
- |
1600 |
- |
|
9 |
N-NH4 /ammonia nitrogen |
mg/dm3 |
33.7 |
5.0 |
- |
|
10 |
N-NО2 /nitrite nitrogen |
mg/dm3 |
0.025 |
0.06 |
- |
|
11 |
N-NО3 /nitrate nitrogen |
mg/dm3 |
<0.05 |
20 |
- |
|
12 |
Keldahl nitrogen / N-NH4;+ N орг |
mg/dm3 |
44.8 |
15 |
- |
|
13 |
N org /Organic nitrogen * |
mg/dm3 |
11.1 |
10 |
- |
|
14 |
Total nitrogen / Nt * |
mg/dm3 |
44.87 |
35.06 |
15 |
|
15 |
Soluble phosphates /such as PO4 / |
mg/dm3 |
18.2 |
2 |
- |
|
15.1 |
Soluble phosphates /such as P / |
mg/dm3 |
- |
0.7 |
- |
|
16 |
total phosphorus Рt / as PO4 / |
mg/dm3 |
- |
3 |
- |
|
16.1 |
total phosphorus Рt / as P / |
mg/dm3 |
6.4 |
1 |
2 |
|
Group B Common organic pollution indicators |
|||||
|
17 |
oxidizing capacity |
mg/dm3 |
152 |
40 |
- |
|
18 |
COD |
mg/dm3 |
237 |
100 |
- |
|
19 |
BOD5 |
mg/dm3 |
120 |
25 |
- |
|
20 |
petroleum products |
mg/dm3 |
14 |
0.5 |
- |
|
Group C Indicators for organic substances from industrial enterprises |
|||||
|
21 |
Total extractable substances |
mg/dm3 |
28.4 |
5 |
- |
|
22 |
detergenti |
mg/dm3 |
3.6 |
|
|
|
Group C Indicators for inorganic substances from industrial enterprises |
|||||
|
23 |
Cr chromium total *** |
mg/dm3 |
<0.01** |
Cr+3-1,0 Cr+6-0,1 |
|
|
24 |
Cu / copper*** |
mg/dm3 |
<0.01 |
|
|
|
25 |
Co / cobalt*** |
mg/dm3 |
<0.01 |
|
|
|
26 |
Zn / zinc*** |
mg/dm3 |
0.02 |
|
|
|
27 |
Ni / nickel*** |
mg/dm3 |
<0.01 |
|
|
|
28 |
Cd / cadmium*** |
mg/dm3 |
0.002 |
|
|
|
29 |
Pb / lead*** |
mg/dm3 |
<0.01 |
|
|
N org / Орг.nitrogen * - applies to Group B
Cr t- chromium total **
Protokol №340/16.05.2005г. -RIEW W.Tarnowo ***
* indicators for “sensitive zone”
** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986
*** Regulation № 6 /09.11.2000 on the emission levels for admissible content of harmful and hazardous substances in waste water discharged info the water bodies SG 97/2000 г.
The wasted waters are strongly polluated with high concentration of: BOD5 , COD, Amonia and Organic nitrogen and Total Phosphorus,total extractable substances, petroleum products.
IІ-5. Piesometer at Pischensko marsh – Ground water
Table IІ-5
|
No |
Indicators |
Unit |
Point – Piesometer near Pischensko marsh PM1 |
ELV Regulation 1/2000 |
|
|
|
|
|
|
ET |
PT |
|
1 |
2 |
3 |
4 |
5 |
6 |
|
1 |
Geographic coordinates |
grad |
430 39.990’ N 250 12.951’ E |
- |
|
|
2 |
Point No. 13 |
- |
14 |
|
|
|
3 |
Protocols from RIEW Pleven – date of sampling |
No./date |
235 / 18. 05.2005 г. sample taken on 19.04.2005 |
- |
|
|
4 |
Temperature |
0С |
11.6 |
|
|
|
5 |
рН |
- |
7.05 |
|
|
|
6 |
Dissolved oxygen |
mg/dm3 |
1.81 |
|
|
|
7 |
Saturation with О2 |
% |
28.1 |
|
|
|
8 |
Suspended solids |
mg/dm3 |
53 |
|
|
|
9 |
Dissolved substances |
mg/dm3 |
1212 |
|
|
|
10 |
Total dry residue |
mg/dm3 |
1265 |
|
|
|
11 |
Electrical conductivity |
MS/cm2 |
1280 |
|
|
|
12 |
N-NH4 /ammonia nitrogen |
mg/dm3 |
2.8 |
0.12 |
1.2 |
|
13 |
N-NО2 /nitrite nitrogen |
mg/dm3 |
0.031 |
0.025 |
0.125 |
|
14 |
N-NО3 /nitrate nitrogen |
mg/dm3 |
<0.05 |
10 |
30 |
|
15 |
Soluble phosphates /such as PO4 / |
mg/dm3 |
0.05 |
0.1 |
1.0 |
|
16 |
total phosphorus / as P / |
mg/dm3 |
- |
|
|
|
17 |
alkalinity |
mg/dm3 |
11.4 |
|
|
|
18 |
Chlorides Cl / |
mg/dm3 |
46.6 |
30 |
100 |
|
19 |
Sulphates SO4// |
mg/dm3 |
131.0 |
50 |
150 |
|
20 |
Calcium Ca 2+ |
mg/dm3 |
262 |
|
|
|
22 |
Magnesium Mg 2+ |
mg/dm3 |
42.4 |
|
|
|
23 |
Carbonates CO3// |
mg/dm3 |
<5 |
|
|
|
24 |
Hydrocarbonates HCO3/ |
mg/dm3 |
696.0 |
|
|
|
25 |
Hard.total |
|
16.6 |
|
|
|
26 |
Total extractable substances |
mg/dm3 |
<0.1 |
|
|
|
27 |
Mn /total manganese |
mg/dm3 |
1.2 |
0.02 |
0.05 |
|
28 |
Fe/ total iron |
mg/dm3 |
|
0.05 |
0.2 |
|
29 |
Cu / copper*** |
mg/dm3 |
<0.01 |
0.03 |
0.1 |
|
30 |
Zn / zinc*** |
mg/dm3 |
0.01 |
0.2 |
1.0 |
|
31 |
Pb / lead*** |
mg/dm3 |
<0.01 |
0.03 |
0.2 |
|
32 |
Na |
mg/dm3 |
20.9 |
50 |
100 |
|
33 |
K |
mg/dm3 |
7.1 |
|
|
|
34 |
Redocs pot. |
mV |
28.9 |
|
|
|
35 |
Alfa-HCH |
Mg/l |
<0.01 |
|
|
|
36 |
Beta- HCH |
Mg/l |
<0.01 |
|
|
|
37 |
Gama- HCH |
Mg/l |
<0.01 |
|
|
|
38 |
Delta- HCH |
Mg/l |
<0.01 |
|
|
|
39 |
Aldrin |
Mg/l |
<0.01 |
|
|
|
40 |
o,p DDE |
Mg/l |
<0.01 |
|
|
|
41 |
P,p DDE |
Mg/l |
<0.01 |
|
|
|
42 |
o,pDDD |
Mg/l |
<0.01 |
|
|
|
43 |
P,p DDD |
Mg/l |
<0.01 |
|
|
|
44 |
O,p DDT |
Mg/l |
<0.01 |
|
|
|
45 |
P,p DDT |
Mg/l |
<0.01 |
|
|
|
46 |
DIeldrin |
Mg/l |
<0.01 |
|
|
|
47 |
Endrin |
Mg/l |
<0.01 |
|
|
* Regulation №1 of the MOEW, MRDPW,MH and MI dated 07.07.2000 on the studying of the use and conservation of grund water, SG 57/ 2000
** ЕT – ecological threshold
*** PT – pollution threshold
The ground waters are with:
N-NH4 /ammonia nitrogen – over PT – 2.33 times
N-NO2 //nitrite nitrogen – over ET – 1.24 times
Mn /total manganese - over ET – 24 times
Chlorides Cl - over PT -1.55 times
Sulphates SO4// – over ЕT 2.62 times, 89% of PT
ANNEX 2.1.2
HYDROCHEMICAL MONITORING
II Kalimok-Brushlen Protected Area
period – 18.04.2005 through 27.04.2005
II Kalimok-Brushlen Protected Area - period – 18.04.2005 through 27.04.2005
II-1. the Danube in the flooded wetlands area – surface water- Table IІ-1- ND
IІ-2. Brushlen marh and the fisheries – surface water
Table II-2
|
No |
Indicators |
Unit |
P o i n t s |
ELV
Cathegry III |
|||
|
|
|
|
Brushlen marsh, north of the irrigation channel, north of the main drainage channel, near the pipe |
Fish farms Nova Cherna, East zone, pool 12, concrete sluice |
Fish farms Nova Cherna, East zone, pool 15, concrete sluice near a concrete fish trap |
Fish farms Nova Cherna, East zone, pool 6, concrete sluice near a concrete fish trap |
|
|
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
|
1 |
Geographic coordinates |
|
440 00.411’ N 260 19.781’ E |
440 01.459’ N 260 29.359’ E |
440 01.545’ N 260 30.017’ E |
440 01/579//N 26030.236’E /440 01.630/ N 260 30.029’ E |
- |
|
2 |
Point No. |
- |
5 |
6 |
7 |
8 |
|
|
3 |
Protocols from RIEW Russe – date of sampling |
No./date |
197/27.04. 2005 sample 5 taken on 18.04
|
213/27.04.2005. sample taken on 19.04 |
214 /27.04.2005. sample taken on 19.04 |
215 27.04.2005. sample taken on 19.04 |
- |
|
Group A Common physical and inorganic parameters |
|||||||
|
4 |
Temperature |
0С |
16.8 |
14.1 |
13.9 |
14.1 |
|
|
5 |
рН |
- |
7.56 |
7.93 |
7.8 |
7.86 |
6-9 |
|
6 |
Dissolved O2 |
mg/dm3 |
6.5 |
7.46 |
7.26 |
7.24 |
>2 |
|
7 |
Saturation with О2 |
% |
67.8 |
72.4 |
70.4 |
70.2 |
20 |
|
8 |
Electrical conductivity |
MS/cm2 |
620 |
334 |
338 |
319 |
- |
|
9 |
Suspended solids |
mg/dm3 |
22 |
28 |
18 |
16 |
100 |
|
10 |
turb. |
FAU |
3.07 |
4,19 |
0.84 |
0.95 |
|
|
11 |
Dissolved substances |
mg/dm3 |
|
|
|
|
|
|
12 |
Total dry residue |
mg/dm3 |
430 |
246 |
338 |
- |
|
|
13 |
Fe / total iron |
mg/dm3 |
- |
- |
- |
- |
5.0 |
|
14 |
Mn /total manganese |
mg/dm3 |
- |
- |
- |
- |
0,8 |
|
15 |
N-NH4 /ammonia nitrogen |
mg/dm3 |
0.026 |
0.035 |
0.027 |
0.012 |
5.0 |
|
16 |
N-NО2 /nitride nitrogen |
mg/dm3 |
0.008 |
0.018 |
0.011 |
0.018 |
0.06 |
|
17 |
N-NО3 /nitrate nitrogen |
mg/dm3 |
0.231 |
0.181 |
0.423 |
0.710 |
20 |
|
18 |
Keldahl nitrogen / N-NH4;+ N org |
mg/dm3 |
0.322 |
0.322 |
0.129 |
0.064 |
15 |
|
19 |
N org /Organic nitrogen * |
mg/dm3 |
0.296 |
0.287 |
0.102 |
0.052 |
10 |
|
20 |
Total nitrogen / Nt |
mg/dm3 |
0.561 |
0.521 |
0.563 |
0.792 |
35.06 |
|
20.1 |
Soluble phosphates /such as PO4 / |
mg/dm3 |
0.153- |
0.055 |
0.011 |
0.009 |
2 |
|
21 |
Soluble phosphates /such as P |
mg/dm3 |
0,051 |
0,018 |
0,004 |
0,003 |
0.7 |
|
21.1 |
total phosphorus Рt / as PO4 / |
mg/dm3 |
0.245 |
0.282 |
0.089 |
0.089 |
3 |
|
22 |
total phosphorus Рt / as P / |
mg/dm3 |
0,082 |
0,094 |
0,029 |
0,029 |
1 |
|
Group B Common organic pollution indicators |
|||||||
|
23 |
oxidizing capacity/ |
mg/dm3 |
7.1 |
4.6 |
5.7 |
4.8 |
40 |
|
24 |
COD |
mg/dm3 |
18 |
13 |
22 |
17 |
100 |
|
25 |
BOD5 |
mg/dm3 |
4.07 |
2.05 |
3.29 |
2.3 |
25 |
|
26 |
H |
cm |
83 |
120 |
100 |
80 |
|
N org / Орг.nitrogen * - applies to Group B
** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986
All indicators are proving that waters are corresponding to Cathegory III
IІ-3. Main drainage channel– surface water
Table IІ-3
|
No |
Indicators |
Unit |
P o i n t s |
ELV
Cathegry III |
||||
|
|
|
|
main drainage channel in the middle of Brushlen marsh, downstream of the irrigation channel, concrete road and pipeline |
main drainage channel upstream of the fish farms in the eastern zone |
main drainage channel downstream of the fish farms in the eastern zone, upstream of Turchila river |
main drainage channel upstream of Tutrakan PS |
|
|
|
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
|
|
1 |
Geographic coordinates |
|
44000.408’ N 260 19.820’ E |
440 01.488’ N 260 29.626’ E |
440 01.762’ N 260 31.842’ E |
440 02.428’ N 260 34.353’ E |
- |
|
|
2 |
Point No. |
- |
9 |
10 |
11 |
12 |
|
|
|
3 |
Protocols from RIEW Russe – date of sampling |
No./date |
198 / 27.04.2005 sample taken on 18.04 |
199 / 27.04.2005 sample taken on 18.04 |
200 / 27.04.2005 sample taken on 18.04 |
201/ / 27.04.2005 sample taken on 18.04 |
- |
|
|
Group A Common physical and inorganic parameters |
||||||||
|
4 |
Temperature |
0С |
15.4 |
15.8 |
16.3 |
15 |
|
|
|
5 |
рН |
- |
7.62 |
7.51 |
7.48 |
7.45 |
6-9 |
|
|
6 |
Dissolved O2 |
mg/dm3 |
7.83 |
7.17 |
7.30 |
6.35 |
> 2 |
|
|
7 |
Saturation with О2 |
% |
77.7 |
72.6 |
74.0 |
63.0 |
20 |
|
|
8 |
Electrical conductivity |
MS/cm2 |
504 |
407 |
620 |
477 |
- |
|
|
9 |
turb. |
FAU |
24.3 |
1.74 |
2.29 |
2.85 |
|
|
|
10 |
Suspended solids |
mg/dm3 |
38 |
26 |
14 |
12 |
100 |
|
|
11 |
Fe / total iron |
mg/dm3 |
- |
- |
|
- |
5.0 |
|
|
12 |
Mn /total manganese |
mg/dm3 |
- |
- |
|
- |
0,8 |
|
|
13 |
N-NH4 /ammonia nitrogen |
mg/dm3 |
0.035 |
0.032 |
0.041 |
0.039 |
5.0 |
|
|
14 |
N-NО2 /nitride nitrogen |
mg/dm3 |
0.045 |
0.016 |
0.029 |
0.017 |
0.06 |
|
|
15 |
N-NО3 /nitrate nitrogen |
mg/dm3 |
0.308 |
0.423 |
0.652 |
0.816 |
20 |
|
|
16 |
Keldahl nitrogen / N-NH4;+ N org |
mg/dm3 |
0.516 |
0.451 |
0.387 |
0.258 |
15 |
|
|
17 |
N org /Organic nitrogen * |
mg/dm3 |
0.481 |
0.419 |
0.346 |
0.219 |
10 |
|
|
18 |
Total nitrogen / Nt |
mg/dm3 |
0.869 |
0.890 |
1.07 |
1.09 |
35.06 |
|
|
19 |
Soluble phosphates /such as PO4 / |
mg/dm3 |
0.071 |
0.055 |
0.093 |
0.079 |
2 |
|
|
19.1 |
Soluble phosphates /such as P |
mg/dm3 |
0,023 |
0,018- |
0,031 |
0,026 |
0.7 |
|
|
20 |
total phosphorus Рt / as PO4 / |
mg/dm3 |
0.337 |
0.129 |
0.162 |
0.156 |
3 |
|
|
20.1 |
total phosphorus Рt / as P / |
mg/dm3 |
0,112- |
0,043 |
0,054 |
0,052 |
1 |
|
|
Group B Common organic pollution indicators |
||||||||
|
21 |
oxidizing capacity |
mg/dm3 |
8.2 |
6.2 |
6.1 |
5.6 |
40 |
|
|
22 |
COD |
mg/dm3 |
24 |
18 |
17 |
16 |
100 |
|
|
23 |
BOD5 |
mg/dm3 |
4.48 |
3.57 |
3.72 |
2.62 |
25 |
|
|
24 |
H |
cm |
98 |
410 |
120 |
480 |
|
|
N org / Орг.nitrogen * - applies to Group B
** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986
All indicators are proving that waters are corresponding to Cathegory III
IІ-4. Turchila river – surface water
Table IІ-4
|
No |
Indicators |
Unit |
Point Turchila river, bridge over the Tutrakan-Ruse road |
ELV Cathegry III |
|
1 |
Geographic coordinates |
|
440 00.912’ N 260 31.915’ E |
- |
|
2 |
Point No. 13 |
- |
13 |
|
|
3 |
Protocols from RIEW Russe – date of sampling |
No./date |
216 / 27.04.2005 sample taken on 19.04 |
- |
|
Group A Common physical and inorganic parameters |
||||
|
4 |
Temperature |
0С |
14.8 |
|
|
5 |
рН |
- |
7.96 |
6-9 |
|
6 |
Dissolved O2 |
mg/dm3 |
8.91 |
>2 |
|
7 |
Saturation with О2 |
% |
88.4 |
20 |
|
8 |
Electrical conductivity |
MS/cm2 |
722 |
- |
|
9 |
turb |
FAU |
8.89 |
|
|
10 |
Suspended solids |
mg/dm3 |
36 |
100 |
|
11 |
Fe / total iron |
mg/dm3 |
- |
5.0 |
|
12 |
Mn /total manganese |
mg/dm3 |
- |
0,8 |
|
13 |
N-NH4 /ammonia nitrogen |
mg/dm3 |
0.018 |
5.0 |
|
14 |
N-NО2 /nitride nitrogen |
mg/dm3 |
0.006 |
0.06 |
|
15 |
N-NО3 /nitrate nitrogen |
mg/dm3 |
0.887 |
20 |
|
16 |
Keldahl nitrogen / N-NH4;+ N org |
mg/dm3 |
0.451 |
15 |
|
17 |
N org /Organic nitrogen * |
mg/dm3 |
0.433 |
10 |
|
18 |
Total nitrogen / Nt * |
mg/dm3 |
1.34 |
35.06 |
|
19 |
Soluble phosphates /such as PO4 / |
mg/dm3 |
0.325 |
2 |
|
19.1 |
Soluble phosphates /such as P |
mg/dm3 |
0.065 |
0.7 |
|
20 |
total phosphorus Рt / as PO4 / |
mg/dm3 |
0.601 |
3 |
|
20.1 |
total phosphorus Рt / as P / |
mg/dm3 |
0.17 |
1 |
|
Group B Common organic pollution indicators |
||||
|
21 |
oxidizing capacity |
mg/dm3 |
8.2 |
40 |
|
22 |
COD |
mg/dm3 |
25 |
100 |
|
23 |
BOD5 |
mg/dm3 |
4.78 |
25 |
|
24 |
H |
cm |
60 |
|
N org / Орг.nitrogen * - applies to Group B
** Regulation №7 of the CEP, MH the CTU dated 08.08.1986 on the indicator and levels for determination of the quality of flowing surface water, SG 96/ 1986
All indicators are proving that waters are corresponding to Cathegory III